气源温度与解吸过程对变压吸附制氧效果的影响.pdf

学兔兔 化 工 进 展 - 574· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第4期 气源温度与解吸过程对变压吸附制氧效果的影响 张 辉，刘应书，翟 晖，刘文海，曹红程 (北京科技大学机械工程学院气体分离工程研究所，北京 100083) 摘 要：研究了气源温度和解吸条件对制氧效果的影响，结果表明：细长解吸管路会导致吸附塔内氧浓度波前沿 在吸附周期内极易穿透床层，在产氧期及间歇期都会有低浓度氧流入储氧罐，造成氧浓度和流量下降；较高的气 源温度有利于分子筛解吸再生，在15~65℃内，平均每升高10℃，产氧体积分数可以提高1．2％。 关键词：温度；解吸；制氧；变压吸附 中图分类号：TQ 028．1 文献标识码：A 文章编号：1000—6613(2009)04—0574—05 Effect of air temperature and desorption on oxygen generation by pressure swing adsorption ZHANGHui，LIUYingshu，ZHAIHui，LIUWenhai，CAOHongcheng (Institute of Gas Separation Engineering，School of Mechanical Engineering，University of Science and Technology Beijing，Beijing 100083，China) Abstract：The temperature of feed air and desorption parameters，such as the inner diameter and length of the pipe for desorption were measured in oxygen generation by pressure swing adsorption．The result showed that thinner and longer pipe could lead to more easy penetration of oxygen in adsorption bed during the adsorption step．Oxygen with a lower concentration would reach the top of the adsorption bed during adsorption and desorption，resulting in lower oxygen concentration and decreased flow rate．The feed air with a higher temperature would enhance the regeneration of molecular sieve，and the oxygen concentration increased by 1．2％per 10℃ between 15℃ and 65℃． Key words：temperature；desorption；oxygen generation；pressure swing adsorption 自20世纪70年代以来，分子筛吸附性能的提 地势高，大气稀薄，氧分压低。这两者对制氧过程 高促进了变压吸附制氧的迅猛发展【Jj，使其在医疗 影响较大，如