耐氧化芳香聚酰胺纳滤膜的研究进展.pdfVIP

学兔兔 化 工 进 展 ·2240· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2011年第30卷第l0期 0 0 0 0 0鹳 e 《进展与述评； 气 ／ ‘ 气 耐氧化芳香聚酰胺纳滤膜的研究进展 张兆利，王 枢，郭竹洁，王 娇 (西南交通大学生命科学与工程学院，四川 成都 610031) 摘 要：芳香聚酰胺纳滤膜不耐氧化，易被活性氯氧化降解，导致膜性能急剧下降，缩短膜的使用寿命，目前 已成为制约芳香聚酰胺纳滤膜应用和发展的关键问题之一。本文综述了芳香聚酰胺纳滤膜的材料和结构，重点 概述了芳香聚酰胺氯化和膜性能下降的机制，并进一步介绍了近年来耐氧化芳香聚酰胺纳滤膜的研究进展。 关键词：芳香聚酰胺；纳滤膜；活性氯；氧化降解；耐氧化 中图分类号：TQ 028．8 文献标志码：A 文章编号：1000—6613(2011)10—2240—07 Development of the oxidation resistance of aromatic polyamide thin-film composite nanofiltration membranes ZHANGZhaoli，WANGShu，GUOZhuj‘ie，WANGJiao (School ofLife Science and Engineering，Southwest Jiaotong University，Chengdu 610031，Sichuan，China) Abstract：Aromatic polyamide thin—film composite(TFC)nanofiltration(NF)membranes are very sensitive to a chlorine disinfectant．The oxidative degradation takes place under active chlorine conditions．The free chlorine in feed stream can cause degradation of crosslinked aromatic polyamides and ultimately result in the decline of the membrane separation performance，which shortens the membrane life and greatly limits the further application and development of NF membranes ． Series studies of NF materials and structures in recent years are briefly summarized．This review iS focused on the oxidative degradation of aromatic polyamides and the mechanism of the decline of the membrane separation performance．The prospect on the development of the oxidation resistance of aromat