聚乙烯醇共混膜的氢键和相容性.pdfVIP

学兔兔 化 工 进 展 ·1082· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第3 1卷第5期 壳聚糖／聚乙烯醇共混膜的氢键和相容性 祝二斌，辛梅华，李明春，林佳福 (华侨大学材料科学与工程学院，环境友好功能材料教育部工程中心，福建 厦门 361021) 摘 要：采用溶液共混法制备了不同配比的壳聚糖／聚乙烯醇共混膜，通过变温FTIR、TG、DTA、DSC及XRD 等对共混膜的结构、氢键相互作用、热行为和结晶性等进行研究。实验结果表明，共混膜中壳聚糖与聚乙烯醇 间存在强烈的氢键相互作用。氢键的存在使壳聚糖的热稳定性提高，聚乙烯醇结晶性下降，促进壳聚糖与聚乙 烯醇相容。当壳聚糖／聚乙烯醇共混膜的质量比分别为10／0、7／3、5／5、3／7和0／10时，共混膜的初始分解温度分 别为244℃、257℃、260℃、262℃和285℃。聚乙烯醇熔融温度从 193℃下降到 173℃，玻璃化转变温 度从74．2℃上升至80℃，结晶度墨从3．57％下降到1．97％。 关键词：壳聚糖；聚乙烯醇；氢键；相容性；热行为 中图分类号：O 636．1 文献标志码：A 文章编号：1000—6613(2012)05—1082—06 Hydr0gen-b0nding and compatibility of chit0san／pOlyVinyl alcohol blend films ZHUErbin，XINMeihua，LIMingchun，LINYiafu (Engineering Research Center ofEnvironment—Friendly Functional Materials，Ministry ofEducation，College of Material Science and Engineering，Huaqiao University，Xiamen 361021，Fujian，China) Abstract：Chitosan(CS)／polyvinyl alcohol(PVA)blend films with different compositions were prepared by solution casting technical using 2％ acetic acid／water as a solvent．The structure， hydrogen-bonding，thermal behaviors and crystallization of CS／PVA blend films were systematically investigated by vailable temperature FTIR，TGA，DTA，DSC and WXRD．It indicated that strong hydrogen．bonding interactions existed between CS and PVA，leading to the increase in therlYla1 stabilitV of CS，the decrease in crystallinity of PVA，and enhancement of the compatibility of CS and PVA．When the weight ratio of CS／PVA blend films was l0／0，7／3，5