One-Dimensional Helical Homochiral Metal-Organic Framework Built from 2,2′-Dihydroxy-1,1′-binaphthyl-3,3′-dicarboxylic Acid 英文参考文献.docVIP

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One-Dimensional Helical Homochiral Metal-Organic Framework Built from 2,2′-Dihydroxy-1,1′-binaphthyl-3,3′-dicarboxylic Acid 英文参考文献.doc

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One-Dimensional Helical Homochiral Metal-Organic Framework Built from 2,2′-Dihydroxy-1,1′-binaphthyl-3,3′-dicarboxylic Acid 英文参考文献

Polymers 2011, 3, 1866-1874; doi:10.3390/polym3041866 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article One-Dimensional Helical Homochiral Metal-Organic Framework Built from 2,2′-Dihydroxy-1,1′-binaphthyl-3,3′- dicarboxylic Acid Koichi Tanaka 1,*, Yuki Kikumoto 1 and Motoo Shiro 2 1 Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan 2 Rigaku X-ray Laboratory, 3-9-12 Matsubara-cho, Akishima, Tokyo 196-8666, Japan; E-Mail: shiro@rigaku.co.jp * Author to whom correspondence should be addressed; E-Mail: ktanaka@kansai-u.ac.jp; Tel.: +81-06-6368-0861; Fax: +81-06-6368-0861. Received: 17 August 2011; in revised form: 19 September 2011 / Accepted: 31 October 2011 / Published: 1 November 2011 Abstract: A homochiral metal-organic framework (MOF) based on enantiopure (R)-2,2′-dihydroxy-1,1′-binaphthyl-3,3′-dicarboxylic acid was synthesized. X-ray crystal diffraction studies revealed that the MOF adopts a one-dimensional infinite right-handed helical tubular structure along the a-axis, which serves as a host for the inclusion of guest dimethylformamide (DMF) molecules. Keywords: homochiral metal-organic framework; chiral ligand; helix structure; one-dimensional network 1. Introduction The field of metal-organic frameworks (MOFs) has grown explosively in recent years [1-8]; numerous studies have been reported owing to the potential applications of MOFs in gas storage [9-15], separation [16-23], luminescent materials [24-32], and heterogeneous catalysis [33-41]. While several MOFs have been discovered so far, only a few examples of chiral MOFs for enantiomer separations or heterogeneous asymmetric catalysis have been investigated [42]. We recently reported the synthesis of a Polymers 2011, 3 1867 novel two-dimensional homochiral MOF, (R)-MOF-1, from (R)-2,2′-dihydroxy-1,1′-bin