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Optical Sensor for Characterizing the Phase Transition in Salted Solutions 英文参考文献
Sensors2010,10,3815-3823;doi:10.3390/s100403815
OPENACCESS
sensors
ISSN1424-8220
/journal/sensors
Article
OpticalSensorforCharacterizingthePhaseTransitioninSalted
Solutions
,MarioMarchetti
R′emyClaverie 1,?,MarcD.Fontana 2,IvanaDuriˇckovi′c 1,2,PatriceBourson 2 1
andJean-MarieChassot
2
′
′
1
LaboratoireR′egionaldesPontsetChauss′eesdeNancy,Centred’EtudesTechniquesdel’Equipement
del’Est–71ruedelagrandehaie,54510Tomblaine,France
2
LaboratoireMat′eriauxOptiques,PhotoniqueetSyst`emes,UniversityPaulVerlaineofMetzand
Sup′elec–2rueEdouardBelin,57070Metz,France;E-Mails:marc.fontana@metz.supelec.fr
(M.D.F.);bourson@metz.supelec.fr(P.B.)
?
Authortowhomcorrespondenceshouldbeaddressed;
E-Mail:remy.claverie@developpement-durable.gouv.fr;Tel:+33-383-183-144;
Fax:+33-383-184-141.
Received:11February2010;inrevisedform:27February2010/Accepted:17March2010/
Published:14April2010
Abstract:Weproposeanewopticalsensortocharacterizethesolid-liquidphasetransition
insaltedsolutions. TheprobemainlyconsistsofaRamanspectrometerthatextractsthe
vibrationalpropertiesfromthelightscatteredbythesaltymedium. Thespectrumofthe
O?HstretchingbandwasshowntobestronglyaffectedbytheintroductionofNaClandthe
temperaturechangeaswell.AparameterS de?nedastheratiooftheintegratedintensities
D
oftwopartsofthisbandallowstostudythetemperatureandconcentrationdependencesof
thephasetransition. Then,aneasyandef?cientsignalprocessingandtheexploitationof
amodi?edBoltzmannequationgiveinformationonthephasetransition. Validationswere
doneonsolutionswithvaryingconcentrationofNaCl.
Keywords:Ramansensor;phasetransition;saltedsolution
Sensors2010,10
3816
1. Introduction
Ramanspectroscopy(RS)isawell-establishedtechniquetostudythevibrationalpropertiesofsolid,
liquidsorgas,inrelationwiththestructureandthepropertiesofthesubstance.Itislessfrequenttouse
RSasaprobeofphysicalcharacteristicsorpropertiesofasubstance.Ramansensorsareabletoemploy
recenttechnicalimprovementsinthedevelopmentofsmartapparat
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