原烟在线近红外光谱模型转移研究.pdfVIP

27 杨凯等 原烟在线近红外光谱模型转移研究 原烟在线近红外光谱模型转移研究 杨凯1 ，刘鹏2 ，王维妙1 ，石超2 ，何利波2 1 上海烟草集团有限责任公司技术中心，上海市杨浦区长阳路717 号2仪用82; 2 上海创和亿电子科技发展有限公司，上海市杨浦区控江路和平花园 200092 摘 要:为实现原烟在线近红外光谱模型的转移，利用两台多通道阵列检测器型在线近红外光谱仪作为主从仪器对烟叶烟碱指标 的模型转移进行研究。将主仪器采集的光谱进行偏移量转移和斜率截距法转移以及从仪器采样重新建模等三种方法掏建从仪器 模型，比较三者的预测效果。结果显示:偏移量转移、斜率截距法转移、重新建模与主仪器模型相比，模型内部参数有较好的一致 性;外部验证平均相对误差结果表明偏移量转移的平均相对误差较大，而斜率截距法转移和重新建模的外部平均相对误差水平非 常接近，说明可利用转移模型替代重新建模对样本进行预测。 关键词:原姻;阵列检测器;在结近红外;偏移量转移;斜率截距法 doi:l0. 3969/j. ÏSSD.l例4-5708. 20口.06. 创际 中图分类号:TS47 文献标识码:A 文章编号:U刷-57鹏(2012)06峭27..05 Study on transferring of raw tobacco online NIR model YANG Kai 1 ,UU Peng2 ,WANG Wei-miao 1 ,SHI Chao ,HE Li_bo2 1 Technology Center of Shanghai Tobacco Group CO. LTD. , Shanghai , 2∞82 ， China; 2 Shanghai Micro-Vision Technology LT且， Shanghai , 2仅用92 ， China Abstract: In order to realize transferring of raw tobacco online NIR model , two multi -channel photo diode array (PDA) detector online near i曲ared (NIR) spectrome忧rs were applied 臼 master and slave instruments. Predicting results of three methods , i. e. (1) offset transfer , (2) slope intercept method with spectra of m幽ter instrument , and (3) re- modeling slave instrument model were compared. Results showed 由at compared with master instrument model , intemal parameters of slave instrument model built by re-modeling , offset transfer and slope intercept method all had good coher- ence. Extemal validation results showed that mean relative error (MRE) of offset transfer method w部 big. Both slope intercept and re-modeling method had similar and preferable MRE , demonstrated that transfer model by slope intercept method could replace re-modeling model for sample prediction.