Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)–Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand.docVIP

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Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)–Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand.doc

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Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)–Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand

Polymers 2012, 4, 1613-1626; doi:10.3390/polym4031613 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)–Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand Takashi Okubo 1,*, Naoya Tanaka 1, Haruho Anma 1, Kyung Ho Kim 2, Masahiko Maekawa 1 and Takayoshi Kuroda-Sowa 1 1 School of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, Japan; E-Mails: nekonikobam@yahoo.co.jp (N.T.); nma_chem_sci_kindai@yahoo.co.jp (H.A.); maekawa@rist.kindai.ac.jp (M.M.); kuroda@chem.kindai.ac.jp (T.K.S.) 2 Department of Materials Science and Engineering, Kitami Institute of Technology, 165 Koen-cho, Kitami, Hokkaido 090-8507, Japan; E-Mail: khkim@mail.kitami–it.ac.jp * Author to whom correspondence should be addressed; E-Mail: okubo_t@chem.kindai.ac.jp; Tel.: +81-6-6730-5880-4117; Fax: +81-6-6723-2721. Received: 2 July 2012; in revised form: 5 September 2012 / Accepted: 10 September 2012 / Published: 20 September 2012 Abstract: One-dimensional (1D) halide-bridged Cu(I)–Ni(II) heterometal coordination polymers containing a hexamethylene dithiocarbamate (Hm-dtc) ligand have been synthesized and crystallographically characterized. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the coordination polymers were estimated using UV-Vis-NIR and photoelectron spectroscopies, and it was revealed that these coordination polymers have appropriate HOMO levels for use as dye sensitizers. Direct-current electrical conductivity measurements and impedance measurements indicated that these 1D Cu(I)–Ni(II) heterometal coordination polymers were insulators (σ300K 10?12 S cm?1). In addition, the coordination polymers were used as sensitizing materials in dye-sensitized solar cells (DSSCs). DSSCs with 1D Cu(I)–Ni(II) he