水溶性铑络合物催化1-十二碳烯氢甲酰化反应器构型的初步探索.pdfVIP

Chin酣J， Chem, E，略， 10 (1) 45-51 (2日 02) Preliminary Exploration of the Reactor Configuration for Hydroformylation of l-Dodecene Catalyzed by Water Soluble Rhodium Complex fQ03 内 MAOZ血ha(毛在砂)忡， BI Xi即an(毕新制， YU Gengzhi(禹耕划， ZHANGYo吨qi蛐g(张永剧， YANG Chao(杨超)酬d WANG Rong(主馨) lnstitute of Pro咐，日ngin明ing (formerly lnstitute of Chemic.1 Met.Uurgy) , Chin附Ac时棚lY of Sden耐，胁IJlng I剧lO80， Chin. Abstract Hydroformylation 011田dod四:enew制向叫ied in a biph制ic sy盹em USlllg wa.ter..脚luble rhod川mcomple这 阳α(CO)(TPPTSb] 踹峭.I)lit ìn ‘he preseo1仰。f cetyl trìmethyl 阳mOnÍUDl bromlde 描灿rfa.cta.nt 阳 ωhance the reaction ratιEfforts were devoted to ìmprove the perfonnance of hydroformyla.tion by exploring 阳阳 con6guration whicb 咄hanced the 皿ixing， dispersion and intè叩hase nla且 tra.nÍer. Experimcn阳 were carrÎw out ìn a 0,5L a.utodave a.t the total pr回$ure of 1.1MP邑 and temp时ature from 363 K to 373 K. Severa.l $urface a.盯ation con何町a.tions were tested ,and h鸣her hydroformylation rate with higher norm时fbra.nched aldehyde ra.tio produced m胆 achieved. The e.xperienc咽 suggeat that improvtXl rea.ctor çonfigura.tion by taking reactioD. engÌl附nng me嗣旧制 ω benefìda.l to better pro愣辅 ecollomy in alkene hydrofor皿ylation. Keywords l..!od，啊。肘， biph8l:lÎC hydro(orrn.yla.tion , g制炉lîquíd~lîquid rea.ctor , rea.ctíon en斟肌盹ring， surfaεe 脚ra盼 tion , eml叫.sifica.tio隙， n/i ra.tiQ 1 日JTRODUCTION thecomm凹cialization of bipha.sic hyd1oformylation of Hydroformylation of olefìns is an import剖1t com- hlghe1 olefins. merdal p1ocess for production of aldehydes and al- Chen et a/,