机械合金化制备Ag-Cu28合金过程的研究.pdfVIP

学兔兔 第27卷第1期 粉末冶金技术 Vo1．27．No．1 2009年2月 Powder Metallurgy Technology Feb．2009 机械合金化制备Ag—Cu28合金过程的研究* 李良锋一 丘 泰 杨 建 李晓云 (南京工业大学材料科学与工程学院，南京 210009) 摘 要： 采用机械合金化法制备Ag-Cu2 二元共晶合金，通过正交试验研究球磨机转速、球料比及过程控制 剂对合金化过程的影响，利用XRD、SEM、TG-DSC等方法对球磨粉料的物相组成、微观形貌、熔化特性等进行 表征。结果表明：Ag、Cu经过30h球磨，生成了Ag(Cu)过饱和固溶体，其熔化温度为783．812，该合金属于亚 稳态结构，退火处理后以富银、富铜相形式存在。合金化过程中，硬脂酸作为过程控制剂的加入可以有效地减 小颗粒尺寸，但对合金化不利。 关键词：正交试验；过程控制剂；Ag—Cu2R合金；机械合金化 Study on Ag-Cu28 alloys synthesized by mechanical alloying Li Liangfeng，Qiu Tai，Yang Jian，Li Xiaoyun (College of Materials Science and Engineering，Nanjing University of Technology，Nanjing 210009，China) Abstract：Ag-Cu28 eutectic alloys have been prepared by mechanical alloying with mixed powders of Ag and Cu．The effects of milling speed，ball—to-powder weight radio and PCA on alloying process have been studied by orthogonal experiment．The phase compositions，microstructures and melting properties of the powders were studied by XRD， SEM and TG-DSC．The results show that Ag-Cu supersaturated solid solution alloys can be obtained by milling powders of Ag and Cu for 30h．The lowest melting point is 783．8C ．Ag—Cu28 alloy is metastable state，the composition of alloy is Ag—rich and Cu—rich phase after aging treatment．The steari acid as PCA can refine powder size effectively，but it is a disadvantage factor for alloying． Key words：orthogonal experiment；PCA ；Ag—Cu28 alloy；mechanical alloying 目前银系钎料主要以纯Ag、Ag—Cu2 Ag—cu50 方法，可以在固态常温下获得不互溶体系或熔点相 等为主，由于具有低熔化温度、高强度、优良的加工