熔盐电脱氧法制备金属Cr粉的研究.pdfVIP

维普资讯 学兔兔 第 18卷第2期 粉 末 冶 金 工 业 Vo1．18 No．2 2008年4月 P0WDER METALLURGY INDUSTRY Apr．2008 熔盐电脱氧法制备金属Cr粉的研究 赵炳建，王 岭。戴 磊，崔广华，李跃华，朱立光 (河北理工大学 化工与生物技术学院，河北 唐山 063009) 摘 要：以烧结的Cr O。片体为阴极、高密度石墨碳棒为阳极，在 820℃的CaCl 熔盐中，2．8 V电压下进行电脱氧反应，制得金属铬。研究了烧结温度、电解时间对电解反应的影响，用电 子扫描显微镜(SEM)分析了900℃、1 200℃烧结试样电解前后的微观形貌；XRD分析了电解 产物的相组成。结果表明：试样的烧结温度越高，孔隙率越低，电脱氧反应速率越慢，产物的颗 粒越大；电解还原是从外向内进行的；扩散过程是影响电脱氧反应速率的重要因素。 关键词：Cr2O3；电脱氧；Cr；熔盐；扩散 ． 中图分类号：TF111．52 文献标识码：A 文章编号：1006—6543(2008)02—0023—05 RESEARCH oF PREPARATIoN oF Cr BY ELECTRODEOXIDATIoN IN MoLTEN SALT ZHAO Bing-jian，WANG Ling。DAI Lei，CUI Guang-hua。LI Yue-hua，ZHU Li。guang (College of Chemical Engineering and Biotechnology，Hebei Polytechnic University，Tangshan Hebei 063009，China) Abstract：Metallic Cr was prepared by electrodeoxidation from Cr2 03 in molten CaC12 at 82 0℃ under a voltage of 2．8 V．During electrolysis Cr2 O3 pellets sintered at different temperature were used as cathode，while high density graphite rod was used as anode．The effect of sinte— ring temperature and the time of electrolysis on the process was investigated．The microstruc— ture of the Cr2 03 pellets before and after sintering was investigated by SEM．The phase com— position of products electrolysed under different conditions were examined by XRD．The re— sults show that the higher the sintering temperature，the lower the porosity，the lower the speed of electro—deoxidation and the larger the grain of product is．