琥珀酸双酯磺酸钠类反应型表面活性剂的合成论文.pdfVIP

全国第十三次工业表面活性剂研究与开发会议 琥珀酸双酯磺酸钠类反应型表面活性剂的合成 1,2 1 3 胡艾希 陈学伟 姚志钢 1.湖南大学化学化工学院 湖南 长沙 410082 2.华南理工大学化工与能源学院 广东 省绿色化学产品技术重点实验室 广东 广州510640 3.邵阳学院 湖南 邵阳 422000 摘要 合成了琥珀酸双酯磺酸钠类阴离子反应型表面活性剂 马来酸酐经单酯化 O- 烷基化 选择性磺化反应得到了琥珀酸双酯磺酸钠类表面活性剂 马来酸酐与脂肪醇在90 下反应3 h 得 到马来酸单酯 在碳酸钠 Et N 和 CH COCH 存在下 单酯与丙烯基氯 50 或异丁烯基氯 3 3 3 65 反应6 h 得到马来酸双酯 双酯与亚硫酸氢钠在 120 下反应3 h 得到目标产物 产物 1 经 H NMR 和IR 表征 符合结构特征 关键词 反应型表面活性剂 合成 琥珀酸双酯磺酸钠 Synthesis of Reactive Surfactants of Sodium Sulfosuccinic Diesters 1 1 2 HU Ai-xi ,CHEN Xue-wei ,YAO Zhi-gang 1.College of Chemistry and Chemical Engineering Hunan University Changsha 410082 , Hunan , China 2.The School of Chemical Energy Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China; 3. Shaoyang College , Shaoyang 422000 , Hunan , China Abstract Anionic reactive surfactants of sodium sulfosuccinic diesters were synthesized. Surfactants of sodium sulfosuccinic diesters were synthesized from maleic anhydride by monoesterification, O- alkylation and selective sulfonation. Maleic anhydride was reacted with fatty alcohols at 90 for 3 h to produce maleic monoesters The monoesters were reacted with ally chloride or isocrotyl chloride in the presence of sodium carbonate, Et N and CH COCH for 6 h at 50 and 65 respectively to obtain 3 3 3 maleic diesters Finally, the diesters were reacted with sodium bisulfite at 120 for 3 h to produce sodium sulfosuccinic diesters. The structure of products were confirmed by 1H NMR and IR. Key words : reactive surfactants, synthesis, sodium