n型填充方钴矿热电材料的快速制备研究.pdfVIP

第 31 卷第 12 期 Vo l. 31 No.12 无机材料学报 2016 年 12 月 Journal of Inorganic Materials Dec. , 2016 Article ID: 1000-324X(2016)12-1375-08 DOI: 10.l55411j i Iovestigatioo 00 Quick Fabricatioo of 0-句pe Filled Skutterudites 2 1 2 2 YAOZheng 气 QIU Peng-Fei , LI Xiao-Ya , CHEN Li-Dong (1. University of Chinese Academy of Science哩， Beijing 100049, China; 2. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 , China) Abstract: The cost-effective fabrication of CoSb -based filled skutterudites (SKD) thermoelectric materials is a bot- 3 tleneck issue preventing their successful commercial application. In this study, we employed a simple and scalable process to simultaneously produce a rapid formation and consolidation of n句pe filled skutterudites. This method, consisting of RF-induction melting, quenching and spark plasma sintering (SPS), required less than a half-hour, sig- nificantly shorter 也an conventional process of furnace melting (over 24 h) , annealing (about one week) 扭d SPS. The fabricated bulk SKD materials possessed homogeneous ∞mposition and structures with a good the口noelectric per- formance which are analogous to those materials fabricated according to a conventional process. The homogeneous