耐盐高吸水复合材料的研究.pdfVIP

学兔兔 全国中文核心期刊 新癯建巍 圃 耐盐高吸水复合材料的研究 陈飞，唐宏科 (陕西科技大学 教育部轻化工助剂化学与技术重点实验室，陕西 西安 710021) 摘要：采用丙烯酸(AA)、丙烯酰胺(AM)、丙烯酸甲酯(MA)为单体与有机膨润土复合，通过水溶液共聚法制备复合高吸水性树 脂。考察丙烯酸中和度、单体配比、引发剂用量、交联剂用量、有机膨润土用量、反应温度对复合高吸水性树脂吸水率的影响，获得最 佳聚合反应条件。在此条件下制各的高吸水性树脂对水和O．9％盐水的吸收倍率为850 g／g和120 sis。并用XRD和TGA等对合成 的复合高吸水性树脂结构进行分析。 关键词：高吸水性树脂；水溶液共聚；有机膨润土；吸水率 中圈分类号：TY442 文献标识码：A 文章编号：1001—702X(2010)07—0062-04 Study oR salt-resisting superabsorbent composite CHEN Fei，TANG Hongke (Key Laboratory of Auxiliary Chemistry＆Technology for Chemical Industry，Ministry of Education， Shaanxi University of Science＆ Technology，Xi an 710021，Shaanxi，China) Abstract：The superabsorbent composite was synthesized by aqueous solution copolymerization using acrylic acid(AA)， aerylamide(AM)，methyl acrylate(MA)and organic bentonite，The optimal copolymerization condition was achieved by investigating the effects of factors，such as neutralization of acl-ylic acid，nlononler ratio，content of initiator，content of cross linker，contentof organobentonite，and reaction temperature on the absorbency of the superabsorbent composite resin．The water absorption rate of superabsorbent resin prepared tlnder such conditions was up to 850 g，g for water and 120 幢for O．9％salt water．The structure of composite superabsorbent resin was analyzed by XRD and TGA， Key words：superabsorbent resin；aqueous solution cop0lyme rjzation{organic bentonite；water absorption rate 性树脂中引入非离子极性基团可有效提