铁尾矿烧结多孔保温材料气孔形成的机理研究.pdfVIP

学兔兔 新 建巍 全国中文核心期刊 铁尾矿烧结多孔保温材料号孔形成硇 栅理研究 刘媛媛 一，肖慧 ，李寿德 (1．西安墙体材料研究设计院，陕西西安 710061； 2．西安科技大学 建筑与土木工程学院，陕西 西安 710061) 摘要：介绍以铁尾矿为主要原料，添加发泡剂和粘结剂，烧结制备高孔隙率保温材料的工艺 该材料可通过控制发泡剂的加入 量和烧成温度来调节多孔保温材料的体积密度和孔径大小。x射线衍射分析材料相结构及扫描电镜观测微观结构的结果表明，该保 温材料的主相为非晶相，材料的孔径大小及分布均匀。通过实验，对不同烧成温度下的材料研究分析其气孔形成机理，气孔的形成过 程包括液相生成、气孔形成、气孔长大和气孔上浮4个过程；气孔形成的重要工艺参数为烧成温度在1000～1200℃，在发泡温度附近 温度升降速率必须缓慢，以2～5~C／min为宜。 关键词：铁尾矿；保温材料；气孔；形成机理 中图分类号：33555+1 文献标识码：A 文章编号：1001—702X(2010)04—0047—03 Study on bubble formation mechanism for thermal insulation porous materials of iron tailings LIU Yuanyuan1,21．X／A0 Hui ，LI Shoude (1．Xian Research and Design Institute of Wall＆ Roof Materials，Xian 710061，Shaanxi，China； 2．School of Architecture and Civil Engineering，Xian University of Architecture and Technology，Xian 7 10061，Shaanxi，China) Abstract：In this paper，the sintering process of high porous insulation material was introduced，taking iron—tailings as the main raw material and the foaming agent and binding agent as additives．Both the volume density and the hole diameter of the porous insulation material could be changed by adjusting the amount of the~aming agent and the sintering temperature．The anal— ysis results of X-ray diffraction and scanning electron microscope indicated that the main phase of this insulation material was am orphous phase，and the holeswere evenly distributed with uniform diameter．The formation mechanism of porouswas obtained from the reseal~h and analysis of sam ples of this material under different temperature．Th e bu