非开挖管用改性聚丙烯复合材料制备及性能.pdfVIP

学兔兔 全国中文核心期刊 杆癯建蟓粉 中国科技核心期刊 非开挖管用改性聚丙烯复合材料制备及性链 张平 ，陈枫 ，戴道兴 ，钟明强 (1．浙江工业大学 化学工程与材料学院，浙江 杭州 310014 2．宁波波尔管业开发有限公司，浙江 宁波 315012) 摘要：非开挖改性聚丙烯(MPP)塑料顶管广泛应用于城镇电力电缆、建筑给排水敷设等领域。采用钛酸酯偶联剂(NDZ一105)对 轻质碳酸钙和高岭土进行表面改性处理，成功制备高填充量的PP复合材料和非开挖用MPP管材。SEM分析显示，改性无机填料与 聚丙烯基体的界面结合较好。无机填料在30％填充量下能显著提高复合材料的拉伸强度、弯曲强度、缺口冲击强度和热性能，降低 PP复合材料的生产成本，同时不影响复合材料的加工性能，扩大了其应用领域。 关键词：聚丙烯；非开挖管；碳酸钙；高岭土 中图分类号：TU532~．61；TQ325．1+4 文献标识码：A 文章编号：1001—702X(2012)06—0077—05 Preparation and property of modified polypropylene composites in trenchless pipe ZHANG Pin ～，CHEN Fe ，DAI Daoxing~，ZHONG Mingqianga (1．College of Chemical Engineering and Materials Science，Zhejiang University of Technology，Hangzhou 310014，Zh~iang，China： 2．Ningbo BOER Pipe Indust~Development Co．Ltd．，Ningbo 315012，Zh~iang，China) Abstract：The modified polypropylene(MPP)pipe used for trenchless pipe has great application value OI2 the development and upgrading transformation of power，communication and building drainage industries．In this paper，titanate coupling agent(NDZ-105) was used for the modifications of the calcium carbonate and kaolin clay and the PP composites with high filling ratio and MPP pipes were prepared．Th e SEM analysis showed the good compatibility between the modified fillers and PP matrix．The composite containing 30％ fillers showed improved tensile strength，flexural strength，notch impact strength and thermal prope~ies．Moreover， the composite processability almost had no changed，but the cost of production was reduced．The application field is broadened． Key words：polypropylene：~enchless pipe