D_A星型分子的合成及非线性光学性质_王娟.pdfVIP

2015 34 6 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 1737 D-π-A 12 2 2 1 2 1 1 2 030051 315201 Suzuki D A D-π-A Y NMRESI-MS Z Y (ϕ) 0.77 (σ ) 120GMn 2 2 9.0×10−7 2 cm /GW D-π-A TB 383 A 100066132015 DOI 10.16085/j.issn.1000-6613.2015.06.037 Synthesis and nonlinear optical properties of D-π-A star-shaped molecule 12 2 2 1 2 1 WANG Juan LIU Zhiyang ZUO Hongwen ZHAO Guizhe GE Ziyi LIU Yaqing 1 Polymer Composite Materials Engineering Technology Research Center in Shanxi ProvinceInstitute of Materials Science Engineeringthe North University of ChinaTaiyuan 030051ShanxiChina;2Ningbo Key Laboratory of Silicon and Organic Thin Film Optoelectronic TechnologiesNingbo Institute of Materials Technology Engineering Chinese Academy of SciencesNingbo 315201ZhejiangChina Abstract With phenyl as the centera new D-π-A star-shaped molecule (Y) was designed and synthesized by introducing two electron-donors(D) unit triphenylamine and electron-accepting (A) unit phenanthroimidazole with Suzuki couplingand its structure has been characterized by NMR ESI-MS and elemental analysis. The third order nonlinear optical properties of the compound Y has been studied systematically through UV-Vis abs