电子鼻在石化恶臭检测中的应用.PDFVIP

电子鼻在石化恶臭检测中的应用 摘要 恶臭污染是石化企业不可回避的问题，本研究阐述了恶臭的种类及对 人体的危害，简要介绍了恶臭检测的方法，根据石化产业的污染特点，提 出电子鼻在无量纲臭气浓度检测方面的帮助，通过对某石化厂区不同路段、 厂区和装置的环境大气检测，可以比较其恶臭污染程度，电子鼻传感器对 恶臭成分的响应也与实际情况相符。通过建立模板文件并利用偏最小二乘 回归法 （PLS）可以分别实现对未知样品定性的判断和定量的预测，它对异 常排放也能发出警告。利用电子鼻，可以解决石化产业内部的臭气浓度自 我监控、自我约束和治理方面的很多难题。 关键词：恶臭污染；中石化；电子鼻；无量纲臭气浓度 TheApplicationsofPEN ElectronicNosein Odor Detection of Sinopec Abstract Odor pollution is a problem that petrochemical enterprises can’t dodge. In the paper, categories, damage to human of odor and its detection methods were mentioned. Based on the characteristics of odor pollution in petrochemical industry, PEN e-nose from Germany had advantages in the dectection of odor 第 1 页 共 12 页 degres.As the ambient atmosphere of different sections, factories and devices were detected, the degrees of contamination were able to compare. The results showedthat sensorsresponseto stench componentswasconsistent with the facts. Qualitative judgment and quantitative forecast for unknow samples could be completed through building template files and utilizing partial least squares regression (PLS) , respectively.Additionally, PEN could give the alarm as soon as abnormal air composition was detected. In conclusion, the e-nose from Germany is capable of detecting odor intensity and controlling the pollution. It could promise to become a crucial tool for petrochemical industry in odor governance . Keywords:odorpollution;sinopec;PEN e-nose;odor degres 1.引言 一切刺激嗅觉器官引起人们不愉快感觉及损害生活环境的气味统称为恶臭，具有恶 [1] 臭气味的物质被称为恶臭污染物 。恶臭物质的致臭主要是由于含有特征发臭基团。含 发臭基团的气体分子与嗅觉细胞作用，经嗅觉神经向脑部神经传递信息，从而完成对气 体的鉴别。地球上存在的 200 多万种化合物中，五分之一具有气味，约有 1 万种为重 要的恶臭物质。按化学组成可分成以下五类，一是含硫化合物，如硫化氢、硫醇类、硫 醚类等；二是含氮的化合物，如氨、胺类、酰胺、吲哚类等；三是卤素及其衍生物，如 氯气、卤代烃等；四是含氧的有机物，如酚、醇、醛、酮、有机酸等；五是烃类，如烷 第 2 页 共 12 页 [2] 烃、烯烃、炔烃、芳香烃等 。不同企业排放的恶