冲天炉熔炼过程化学成分变化的热力学建模.pdfVIP

学兔兔 Mar．2011 铸 造 V0I．60 NO．3 FOUNDRY ·243 · 冲天炉熔炼过程化学成分变化的热力学建模 史振忠，周建新 (华中科技大学材料成形与模具技术国家重点实验室，湖北武汉 430074) 摘要：冲天炉是熔炼铸铁最主蓦的设备，由于熔炼过程的机理复杂，影响因素繁多，对冲天炉熔炼过程中元素烧损率 的定量计算以及铁液最终成分的预测一直是个难题=利用热力学的知识建立起了平衡常数法和最小自由能原理法这两 种用于计算铸铁在冲天炉熔炼过程中成分变化的数学模型，总结了这两种模型各自的特点及适用范围，并给出了反求 熔炼过程备种元素烧损率的方法 该热力学模型的建立，对扩大计算机模拟技术在铸造中的应用领域以及定量揭示冲 天炉熔炼规律有着重要的意义。 关键词：冲天炉；熔炼；平衡常数法；吉布斯最小自由能；建模 中图分类号：TG243．3 文献标识码：A 文章编号：1001—4977(201 1)03—0243—04 Thermodynamics Modeling for Chemical Composition Changes in Cupola Melting Process SHI Zhen—zhong，ZHOU Jian—xin (State Key Laboratory of Materials Processing and Die＆Mould Technology，Huazhong University of Science and Technology，Wuhan 430074，Hubei，China) Abstract： Cupola iS the main equipment in the iron melting process．Due to the complex mechanisms and various influence factors，the precise description of the burn out rate and the forecast of the iron liquid finaI composition in cupola melting process are still a problem．The thermodynamic theory was used in this study to establish two mathematicaI models．the equilibrium constant method and the minimization of Gibbs free energY method．for the chemicaI composition calculating in iron melting process。and the features and application areas of the two models have been summarized．What’S more．the measure to compute the lOSS rate of each kind of elements has also been given in this paper．The establishment of the two thermodynamic models has impodant significance to expanding the application of computer simulations in casting fields and quantitatively opening out the regulations in cupola melting process． Key WOrds：cup