壳法用酚醛树脂粘连现象的机理及影响因素.pdfVIP

学兔兔 oct．20O9 VO1．58 NO．10 ·1009· 壳法用酚醛树脂粘连现象的机理及影响因素 熊建民，李远才 (华中科技大学材料科学与工程学院，湖北武汉430074) 摘要：对壳法用酚醛树脂在出现粘连现象前后的玻璃化转变温度进行了检测，结果表明出现粘连现象后树脂的玻璃化 转变温度大幅降低，且树脂的玻璃化转变温度与粘连温度相差无几，说明树脂出现粘连现象时发生了玻璃化转变。并 分析了含水量和软化点对树脂玻璃化转变温度的影响，结果表明含水量的增加会降低树脂玻璃化转变温度和树脂的抗 粘连性能，软化点的升高会提高树脂的玻璃『匕砖变温度和树脂的抗粘连性能。 关键词：壳法；酚醛树脂；粘连；玻璃化转变；含水量 中图分类号：TG221 文献标识码：A 文章编号：1001—4977(2009)10—1009—04 Blocking Mechanism and I nfluence Factors of Phenolic Resin fOr Shell Mould XIONG Jian—min．LI Yuan—cai (Material Science and Engineering College，Huazhong University of Science and Technology Wuhan 430074，Hubei，china) Abstract：The glass transition temperature before and after blocking of phenolic resin for shell mould was researched．and the results indicate that the glass transition temperature of phenolic resin was significantly decreased after blocking and the blocking temperature was close to the glass transition temperature，which shows that the blocking of phenolic resin companied with glass transition．The jnfluence of water content and softening point on glass transition temperature of phenolic resin were also analyzed，and the results show that both the glass transition temperature and the blocking temperature of phenolic resin were reduced with the jncrease of water content of phenolic resin，and increased with the increase of so~ening point of phenolic resin． Key WOrds：shelI mould：phenolic resin；blocking；glass transition；water content 在夏季高温潮湿的环境下，部分壳法用热塑性酚 1 试验部分 醛树脂会出现粘连结块现象，树脂由原本松散的颗粒 或片状转变为带有粘性的整体_ll。树脂粘连后，不但对 1．1 树脂的合成 其称量变得十分困难，而且性能也会严重下降，甚至