BCL-100催化剂制备的PE100管材性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 1110· PETROCHEMICAL TECHN0LoGY 2015年第44卷第9期 材 料 BCL一100催化剂制备的PEIO0管材性能 朱孝恒，郭子芳，苟清强，曹昌文，杨红旭，周俊领 (中国石化 北京化工研究院，北京 100013) [摘要]在Innovene SI艺上采用BCL一100催化剂制备了用于生产PE100管材的树脂(BCL树脂)，利用GPC—IR，”C NMR， DSC，XRD等方法研究了树脂的相对分子质量及其分布、共聚单体含量及分布、结晶性能、力学性能、流变性能以及制备 的PE100管材的性能，并与进口参比催化剂进行了对比。实验结果表明，BCL一100催化剂可生成更多的超高相对分子质量树 脂，己烯共聚率高于参比催化剂，且己烯较多地插入到大分子链段中。BCL树脂的结晶度低，球晶平均尺寸22．0 nln，拉伸弯 曲模量、断裂伸长率、热稳定性、弯曲模量、简支梁抗冲强度均较高，适合开发大VI径低熔垂管材和大容积容器等高等级双 峰制品的专用料。利用BCL树脂生产的PE100管材的性能大幅超过PE100级管材的标准。 [关键词]BCL一100催化剂；PE100管材；双峰聚乙烯 [文章编号]1000—8144(2015)09—1110—05 [中图分类号]TQ 325．12 [文献标志码]A Properties of PEIO0 Pipe Materials Polymerized with BCL-100 Catalyst ZhuXiaoheng，Guo Zifang，Gou Qingqiang，Cao Changwen， Hongxu，ZhouJunlin (SINOPEC Beiiing Research Institute ofChemical Industry，Beijing 100013) [Abstract]The PE 1 00 resin(BCL resin)which could be used as a pipe material was prepared with the BCL一1 00 catalyst in the Innovene S process．The relative molecular mass of the resin and its distribution，comonomer content in the resin and its distribution，its crystallization behavior， mechanical properties，rheological properties and the performances of prepared PE 1 00 pipe were studied by means of GPC—IR， C NMR，DSC and XRD．The performances of BCL resin were compared to another resin synthesized with an imported catalyst．The results showed that，using the BCL-1 00 catalyst，more resin with super-high relative molecular mass could be prepared， the copolymerization rate was higher and the comonomer(hexene)