BCZ催化剂对外给电子体的响应研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第1期 PETROCHEMICAL TECHN0L0GY ·19· BCZ催化剂对外给电子体的响应研究 谭 忠，严立安，周奇龙，徐秀东 (中国石化 北京化工研究院，北京 100013) [摘要]分别以四乙氧基硅烷(TEOS)、二环戊基二甲氧基硅烷(DCPDMS)及复配的TEOS／DCPDMS为外给电子体，考察了 BCZ催化剂的聚合性能及所得聚丙烯的熔体流动速率(MFR)和等规度。实验结果表明，TEOS为外给电子体时BCZ催化剂的 氢调敏感性较好，而DCPDMS为外给电子体所得聚丙烯的等规性能较好；通过调节BCZ催化剂中TEOS／DCPDMS的配比，可 在一定范围内调节聚丙烯的等规度和MFR，当F／(TEOS)：／,／(DCPDMS)=90：10时，可制得MFR(10min)为49．1 g、等规度为 95．6％的聚丙烯；采用TEOS／DCPDMS复配外给电子体时，BCZ催化剂可在较高的聚合温度下制备MFR和等规度均较高的聚 丙烯产品。 [关键词]Ziegler-Natta~化剂；聚丙烯；外给电子体；丙烯聚合 [文章编号]1000—8144(2014)Ol一0019—05 [中图分类号]TQ426．94 [文献标志码]A Studies on Response of BCZ Catalyst in Propylene Polymerization to External Electron Donors TanZhong，YanLi’OH，ZhouQi~ng，XuXiudong (SINOPEC Beijing Research Institute ofChemical Industry，Beijing 100013) l Abstract j The properties of BCZ catalyst with tetraethoxys订ane(TE0S)，dicyclopentyl dimethoxy silane(DCPDMS)or composite TEOS／DCPDMS as the external electron donors，and the melt flow rate(MFR)and isotacticity of the polypropylene prepared with the catalyst were studied．The results indicated that TEOS had fairly good hydrogen sensitivity while DCPDMS showed better stereoselectiVity．By adjusting the ratio of TEOS to DCPDMS for the BCZ catalyst，the MFR and isotacticity of the polypropylene can be regulated in a certain range．When n(TEOS)：n(DCPDMS) 90：10．the polypropylene with MFR(10 min)of49．1 g and isotacticity of 95．6％can be obtained． With DCPDMS／TEOS as the composite extemal electron donors，the BCZ catalyst can be used in