Fe负载量对Fe／y-AI203催化剂催化合成低碳烯烃性能的影响-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第5期 PETR0CHEMICAL TECHN0L0GY ·495· Fe负载量对Fe／y—AI203催化剂催化合成 低碳烯烃性能的影响 邢 军，侯朝鹏，夏国富 (中国石化 石油化工科学研究院，北京 100083) [摘要]采用浸渍法制备了不同Fe负载量的Fe／y—AI：03催化剂，通过XRD、N 物理吸附一脱附、H：一TPR和H 化学吸附等手段对 Fe／y—AI，0 催化剂进行了表征，并在固定床中评价了催化剂的费托合成反应性能。在285℃、2．5 MPa、气态空速4 000 h～、 n(H，)：”(CO)=2的条件下，随Fe负载量的增加，Fe／y—A1：0 催化剂的co／Ju氢活性先增加后降低，在Fe负载量为16％(W)时 活性最高；CO 选择性逐渐增加，c；选择性逐渐降低，C：H 选择性与C：H 选择性相当，而C H 和C H 的选择性优于相应烷烃 的选择性；在Fe负载量9％～21％(W)的范围内，Fe负载量对Fe／?一A1：O，催化剂的低碳烯烃选择性影响不明显。 [关键词]费托合成；铁～一氧化铝催化剂；合成气；低碳烯烃 [文章编号]1000—8144(2013)05—0495—05 [中图分类号]TQ 426 [文献标志码]A Effect of Iron Content in Fe 一AI203 Catalysts on Its Catalytic Performance for Producing Lower Olefins X{ngJun，Hou Chaopeng，Xia Guofu (SINOPEC Research Institute ofPetroleum Processing，Beijing 100083，China) [Abstract]Fe／y-Al203 catalysts with different iron loadings were prepared by wetness impregnation and characterized by means of XRD，N2 adsorption—desorption，H2-TPR and H2 chemisorption．The performances of the catalysts in Fischer．Tropsch synthesis were investigated in a fixed—bed reactor． Under the conditions of reaction temperature 285 ，reaction pressure 2．5 MPa，GHSV 4 000 h。‘ and the mole ratio of H，to CO iS 2，with increasing of the Fe loading，the CO conversion on the Fe ．Al，O catalysts first increased then decreased，and reached the highest value at the Fe mass fraction of 1 6％；the selectivities to CO2 and C；gradually increased and decreased respectively； the selectivities to C2H4 and C2H6 well-matched while the selecti