低黏度离子液体的合成、表征及性能研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2012年第41卷第12期 PETR0CHEMICAL TECHN0LOGY ·1373· 低黏度离子液体的合成、表征及性能研究 徐 凡，王占丽，任保增，汪敬恒 (郑州大学 化工与能源学院，河南 郑州 450001) [摘要]合成了两种以二氰胺根为阴离子的低黏度离子液体l一羟乙基一3一甲基咪唑二氰胺盐和1一丁基一3一甲基咪唑二氰胺盐， 采 ‘H NMR，FTIR，ESI—MS方法对其结构进行了表征。对两种离子液体的密度、黏度、溶解性、熔点和热稳定性等物化性 质及热力学性质进行了考察，初步探讨了它们吸收CO：的性能，并与实验室常用的离子液体1一丁基一3一甲基咪唑四氟硼酸盐 ([Bmim][BF ])进行了对比。实验结果表明，二氰胺根的弓I入可降低离子液体的黏度，在阳离子上引入羟基可增加离子液 体的水溶性，两种离子液体吸收cO 的性能均优于[Bmimj[BF ]。该研究结果为进一步探讨低黏度离子液体在CO 捕集中的 应 提供了基础数据。 [关键词]低黏度离子液体；热力学性质；二氧化碳捕集；溶解度 [文章编号]1000—8144(2012)l2—1373—07 l中图分类号]TQ 252．3 [文献标识码]A Synthesis，Characterization and Properties of Low Viscous Ionic Liquids XuFan，WangZhanli，RenBaozeng，WangJingheng (Institute ofChemical Engineing and Energy，Zhengzhou University，Zhengzhou Henan 450001，China) l Abstract J Two low viscous ionic liquids l一(2一hydroxyethy1)一3一methyl—imidazolium dicyanamide and 1-butyl一3一methylimidazolium were synthesized and characterized by means of H NMR．FTIR and ESI—MS．Their physicochemical and thermodynamic properties，namely density，viscosity， solubility in some solvents，melting point，thermal stability and entropy，were studied．Their performance for CO2 capture was discussed and compared with that of 1-butylimidazolium一3一methy terafluoroborate([Bmim][BF4])．The introduction of dicyanamide groups can decrease the viscosity of the ionic liquids and the introduction of hydroxyl group can increase their water solubility．The performance of the two ionic liquids for CO2 capture are better than that of[Bmim儿BF4 j． [Keywords]low viscous ionic liquid；thermodynamic properties；carbon dioxide capture； solubility 随着温室效