分子筛基液化石油气精脱硫吸附剂的制备与评价-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 T · 286· PETROCHEMICAL TECHN0L0GY 2013年第42卷第3期 分子筛基液化石油气精脱硫吸附剂 的制备与评价 周广林，王晓胜 (中国石油大学(北京)新能源研究院，北京 102249) [摘要]考察了5A，ZSM一5，l3X，NaY等不同类型分子筛的脱硫性能，并以NaY分子筛为载体，采用等体积浸渍法制备_r 以cu ，Zn ，Ag 为活性组分的分子筛基液化石油气(LPG)精脱硫吸附剂，考察了吸附剂的制备条件，并采用固定床反应器 考察了吸附条件对吸附剂脱硫效果的影响。实验结果表明，CuY吸附剂的脱硫性能最好，其适宜的制备条件为：以Cu(NO )， 为活性组分前体，吸附剂中Cu的负载量为9％(W)、浸渍温度6O 、焙烧温度400℃、焙烧时间2 h。在吸附温度为常温、0．6 MPa、液态空速1 h‘。的条件下，CuY吸附剂可使LPG中的硫含量从198 mg／m 降至5 mg／m 以下。 LPG中的硫含量降至5 mg／ m 时，CuY吸附剂的计算穿透硫容为1．23％(W)。 [关键词]液化石油气；二甲基二硫醚；精脱硫；吸附脱硫；分子筛基吸附剂 [文章编号]1000—8144(2013)03—0286—06 [中图分类号]TQ 424．25 [文献标志码]A Preparation and Evaluation of NaY Zeolite—Based Adsorbents for Fine Desulfurization of Liquefied Petroleum Gas Zhou Guanglin，Wang Xiaosheng (New Energy Research Institute，China University ofPetroleum—Beijing，Beijing 102249，China) l Abstract J The desulfurization performance of 5A，ZSM一5，1 3X and NaY zeolites was investigated．A series of adsorbents for the fine desulfurization of liquefied petroleum gas(LPG)were prepared by isovolumetric impregnation with Cu ．Zn or Ag as active constituent and NaY zeolite as support．The conditions of the adsorbent preparation and the effects of adsorption conditions on the desulfurization performance of the adsorbents were studied in a fixed-bed microreactor with industrial etherified C4 as raw materia1．The results show that the best adsorbent CuY can be obtained under the conditions of Cu(NO3)2 as precursor(Cu loading of 9％(w))，impregnati