萃取精馏脱除烃类物流中二甲醚的模拟研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第7期 PETROCHEMICAL TECHN0L0GY ·795· 萃取精馏脱除烃类物流中二甲醚的模拟研究 金 鑫，杨卫胜 (中国石化 上海石油化工研究院，上海 201208) [摘要]以甲醇制丙烯工艺典型的脱丙烷萃取精馏塔进料为研究对象，利用Aspen Plus软件对甲醇萃取精馏脱除烃类产物中二 甲醚杂质的过程进行了模拟研究。在规定塔顶甲醇的含量为3×10 (W)和塔顶丙烷的回收率为99．5％(W)的设计要求下，考 察了萃取精馏塔的溶剂比(甲醇与烃类进料的质量比)、理论塔板数、烃类进料位置、萃取剂(甲醇)进料位置等因素对萃取 精馏塔能耗和分离效果的影响。在满足塔顶二甲醚含量低于1×10 (w)且塔釜丙烯损失尽量少的优化目标前提下，得出较优 的工艺参数：溶剂tk0．3，理论塔板数100，烃类进料位置为第65块塔板，甲醇进料位置为第25块塔板。在该工况下，塔釜丙 烯损失为0．12％(w)。 [关键词]甲醇；二甲醚；丙烯；萃取精馏；Aspen Plus软件；流程模拟 [文章编号]1000—8144(2014)07—0795—05 [中图分类号]TQ 028．1 [文献标志码]A Simulation of Removing Dimethyl Ether in Hydrocarbon Streams by Extractive Distillation J／nXin， Weisheng (S1NOPEC Shanghai Research Institute ofPetrochemical Technology，Shanghai 201208，China) l Abstract]Aimed at the feed stream of depropanizer in methanol—to—propylene process，the process of removing dimethy1 ether in the hydrocarbon stream by extractive distillation with methanol as solvent was simulated by the Aspen Plus software．To meet the requirement of top products(mass content of methanol 3×10 (w)and recovery of propane 99．5~／o(w))，the effects of solvent ratio(the mass ratio of solvent to hydrocarbon stream)，theoretical plate number，hydrocarbon feeding position and solvent feeding position on the reboiler duty of the extractive distillation column were investigated． Under the constraints of dimethyl ether content less than 1×1 0-6(w)in the top products and reasonably low propylene loss in the bottom，the optimized operating conditions were obtained：the solvent ratio o