高温煤气脱硫剂的制备及水汽含量对其脱硫性能的影响-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2010年第39卷第5期 PETROCHEMICAL TECHN0L0GY ·507· 吉 日 煤气脱硫剂的制备及水汽含量对其 同 仙口口L 脱硫性能的影响 宋 瑾，樊惠玲，上官炬，娄艳茹，赵瑞壮 (太原理工大学 煤科学与技术教育部山西省重点实验室，山西 太原 030024) [摘要]以苯乙烯为原料，用乳液聚合法制得聚苯乙烯微球乳液；用FrlR和SEM等手段对聚苯乙烯微球的结构、组成及形态进行 了表征。以钢厂废料赤泥为活性成分、聚苯乙烯微球乳液替代甲基纤维素为造孔剂、黏土为黏结剂，用干混法制得煤气脱硫剂。 在固定床反应器上对煤气脱硫剂的脱硫性能进行了评价，并考察了模拟煤气中水汽含量对其脱硫性能的影响。实验结果表明，在 空速2 000 h_。、温度500℃、模拟煤气气氛的条件下，以聚苯乙烯微球乳液为造孔剂制备的脱硫剂比以甲基纤维素为造孔剂制备 的脱硫剂具有更好的脱硫性能；水汽含量对其脱硫性能有显著的影响，脱硫效率和穿透硫容随水汽含量的增加而降低。 [关键词]乳液聚合；苯乙烯；聚苯乙烯微球；甲基纤维素；造孔剂；煤气脱硫剂；脱硫 [文章编号]1ooo一8144(2010)05—0507～05 [中图分类号]TQ 546．5 [文献标识码]A Preparation of High-Temperature Coal Gas Desulfurizer and Effect of Steam on Its Performance Song Jin，Fan Huiling，Shangguan Ju，Lou Yanru，Zhao Ruizhuang (Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province Taiyuan University of Technology，Taiyuan Shanxi 030024，China) [Abstract] Polystyrene microspheres were synthesized through emulsion polymerization and characterized by means of FTIR and SEM．A sorbent for coal gas desulfurization was prepared using red-mud from steelworks as active component，the synthesized polystyrene microspheres instead of methyl cellulose as pore—forming material and clay as binder．Performance of the prepared coal gas desulfurizer was evaluated in a fixed bed reactor under the conditions of simulated coal gas atmosphere， 500 oC and 2 000 h～． The influence of steam content in feedstock gas on the desulfurizer performanc