裂解气选择加氢工艺的技术进展-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 450· PETR0CHEMICAL TECHN0L0GY 2011年第40卷第4期 裂解气选择加氢工艺的技术进展 黄 龙，戴 伟，田保亮，唐国旗，彭 晖 (中国石化 北京化工研究院，北京 100013) [摘要]裂解气选择加氢是乙烯厂加氧脱除二烯烃和炔烃的一种工艺，相对于现有技术，具有降低下游分离能耗、增加乙烯与丙烯 收率、降低塔釜结焦量等优势。综述了国内外各主要乙烯技术商在裂解气选择加氢领域的专利技术，包括中国石化、IFP、ABB Lummus、Stim—Chemie、Catalytic Distillation Technologies、CRI、Exxon、Linde、Estman和Philips等公司的：I：艺流程、技术特点与近 期的研究进展，并对裂解气选择加氯工艺的未来发展趋势和应用前景进行了分析。 [关键词]裂解气；选择加氢催化剂；乙烯 [文章编号]1000—8144(201】)04—0450—07 [中图分类号]TQ 426．95 [文献标识码]A Technological Progress in Selective Hydrogenati0n of Pyrolysis Gas Huang Long，Dai Wei，Tian Baoliang，Tang Guoqi，Peng Hui (Beijing Research Institute of Chemical Industry，SINOPEC，Beijing 1000t3，China) [Abstract] Pyrolysis gas selective hydrogenation technique can be used in conversing highly unsaturated hydrocarbons to mono—olefin in ethylene plants，which has several advantages，namely low energy consumption in the separation，high ethylene yield and reduction of the fouling in the downstream equipments．The technique has been developed by the main worldwide suppliers for the ethylene production technique，including SINOPEC，IFP，ABB Lummus，Sfim—Chemie，Catalytic Distillation Technologies，CRI，Exxon，Linde，Eastman and Phillips with different patents．This paper describes the processes，their character and recent progress．The trend of development and the prospect of the application for this technique have also been anticipated． [Keywords]pyrolysis gas；selective hydrogenation catalyst；ethylene 乙烯装置是石化行业的龙头，在国民经济中具