电化学基础知识(国外英文资料).docVIP

电化学基础知识(国外英文资料) Basic knowledge of electrochemistry [view the users profile in the data center] [personal data] [message] [post collection] [citation] [citation] [maintenance] -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Preparation of copper, silver and zinc electrode -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- (1) preparation of silver electrodes The silver electrodes will be plated with fine sandpaper, which will be lightly polished to reveal fresh metallic gloss and then washed with distilled water. Dip the two Pt electrodes into the dilute nitric acid solution for a moment and remove the distilled water. Insert wash the electrodes respectively containing silver plating liquid (plating solution composition for 100 ml water and sodium cyanide silver nitrate 1.5 g and 1.5 g) of the small bottle, according to the figure Ⅲ 15   1 connected lines, and two small bottles series, control current 0.3 mA, 1 h, plating white close two silver electrode. (2) preparation of copper electrode The copper electrode in the dilute nitric acid of 1:3 soak for a minute, washed out, as the cathode, in another as the anode copper in the copper plating liquid electroplating (copper plating solution composition for: per liter contains 125 gcuso4 · 5 h2o, 25 gh2so4, 50 ml of ethanol). Circuit shown in figure Ⅲ - 15-1. Control the current to 20mA, with a red Cu electrode with a red surface of 20min, and then put in 0.1000 moles of kg-1cuso4. (3) preparation of zinc electrodes The zinc electrode in dilute sulphuric acid solution soak for a minute, washed out, immersed in mercury or saturated mercurous nitrate solution about 10 s, a layer of