MnO／SAPO-34催化乙醇脱水制乙烯-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第5期 PETROCHEMICAL TECHN0LOGY ·483· MnO／SAPO一34催化乙醇脱水制乙烯 李 娜，陆江银，李国锋，熊丽萍，马记源 (新疆大学 化学化工学院石油天然气精细化工教育部重点实验室，新疆 乌鲁木齐 830046) [摘要]采用浸渍法制备了负载MnO的SAPO一34分子筛(MnO／SAPO一34)催化剂，在固定床反应器中对催化剂的乙醇脱水制 乙烯的催化性能进行了评价，采用低温N 吸附一脱附、XRD、NH 一TPD和H：一TPR等方法对催化剂进行了表征。实验结果表 明，负载适量MnO不会破坏SAPO一34分子筛的骨架结构，但对表面酸性及酸量产生了一定的影响，降低了SAPO一34分子筛上 弱酸与强酸的酸量，有利于提高催化剂的乙醇脱水性能；当MnO负载量为1．29％(W)时，在反应温度300℃、乙醇重时空速 3．16 h 的条件下，乙醇转化率和乙烯选择性分别可以达到99．99％和99．74％。 [关键词]乙醇脱水；乙烯；MnO／SAPO一34催化剂；积碳 [文章编号]1000—8144(2013)05—0483—06 [中图分类号]TQ 221 [文献标志码]A Dehydration of Ethanol to Ethylene over MnO／SAPO-34 Catalyst LiNa，LuJiangyin，Li Guofeng，XiongLiping，MaJiyuan (Key Laboratory ofOilGas Fine Chemicals ofMinistry ofEducation，College ofChemistry and Chemical Engineering Xinjiang University，Urumqi Xinjiang 830046，China) [Abstract]MnO／SAPO一34 catalysts with different MnO loadings were prepared by an impregnation method and characterized by means of N，adsorption—desorption，XRD，NH 一TPD and H2-TPR．The activity of the catalysts in the dehydration of ethanol to ethylene was investigated．The results showed that the addition of an appropriate amount of MnO would not des~oy the framework structure of SAPO一 34 but change its surface acidity．Increasing the ratio of the weak acid sites to the s~ong acid sites on the catalysts would improve the catalyst activity in the ethanol dehydration．Under the optimized conditions of 1．29％(Ⅵ，)MnO／SAPO一34 as the catalyst，reaction temperature of300℃and WHSV of3．16 lr ，the ethanol conversion and ethylene selectivity could reach 99．99％and 99．74％．respectively． [Keywords