Pd-Bi／AI203和Pd-Pb／AI2O3催化剂用于碳四选择加氢除炔的比较-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2012年第41卷第9期 PETR0CHEMICAL TECHN0L0GY ·993· Pd—Bi／AI203和Pd—Pb／AI2O3催化剂用于 碳四选择加氢除炔的比较 乐 毅，杨 栋，朱云仙，徐立英 (中国石化 北京化工研究院，北京 100013) [摘要]对Pd．Bi／AI O 和Pd．Pb／Al O 催化剂在碳四选择加氢除炔中的选择性及再生对催化剂性能的影响进行了比较。实验结 果表明，新鲜的Pd—Bi／A1 O 和Pd—Pb／Al O 催化剂的加氢除炔选择性接近，在总炔烃剩余量小于2 X 10 (W)的条件下，1，3一丁 二烯损失量分别为1．6％(W)和1．7％(W)。再生对Pd—Bi／A1：O 催化剂的影响很大，再生后的Pd—Bi／A1 O 催化剂在反应中很快失 活，而Pd．Pb／AI：O 催化剂经再生后的加氢除炔选择性基本不变。H2．TPR和XPS表征结果显示，Pd—Bi／AI2O 催化剂中的部分氧 化态的Bi物种在再生过程中被还原为金属态，且迁移到了Pd颗粒的表面，使Pd分散度下降，从而导致催化剂的加氢除炔选择 性发生变化。Pd—Pb／A120 催化剂在再生前后的结构稳定。 [关键词]钯一铋催化剂；钯一铅催化剂；碳四选择加氢；催化剂再生；除炔 [文章编号]1000—8144(2012)09—0993—06 [中图分类号]TQ 221．223 [文献标识码]A Comparison Between the Performances of Pd—Bi／AI2O3 and Pd—Pb／AI2O3 Catalysts for Selective Hydrogenation of Crude C4 to Remove Alkynes Yue M， 馏 Dong，Zhu Yunxian，Xu Liying (SINOPEC Beijing Research Institute ofChemical Industry，Beijing 100013，China) l Abstract J The selectivities of Pd—Bi／A1203 and Pd-Pb／A12O3 catalysts f0r the selective hydrogenation of crude C4 to remove the alkynes were compared，and the impact of regeneration on the two catalysts was studied．The results showed that the butadiene loss was 1．6％(w)and 1．7％(w)respectively over the two catalysts with less than 2 X 1 0。(w)of total residual alkynes in the products．The Pd—Bi／Al2O3 catalyst deactivates rapidly after regeneration，but the selectivity of the Pd-Pb／A12O3 catalyst has no differences before and after regeneration．The H2一TPR and XPS results show that the Bi species