含有轴向配体的酞菁金属材料的合成与应用进展.pdfVIP

学兔兔 石 油 化 工 · 1016· PETR0CHEMICAL TECHNOL0GY 2015年第44卷第8期 含有轴向配体的酞菁金属材料的 合成与应用进展 崔 娜，井晓慧，程振华，】、婷婷，朱丽君，夏道宏 (中国石油大学(华东)重质油国家重点实验室，山东 青岛 266580) [摘要]近几年含有轴向配体的酞菁金属材料的合成与应用取得突飞猛进的发展，尤其在太阳能电池材料方面的研究与应用 更为显著。介绍了含有轴向配体的酞菁金属配合物的结构特征，阐述了这类酞菁金属材料在合成方面的研究进展以及在催化 氧化、光盘信息记录、太阳能电池、医学等领域的应用进展，并对其发展前景进行了展望。 [关键词]酞菁金属；轴向配体；合成；光电材料 [文章编号]1000—8144(2015)08—1016—08 [中图分类号]TQ 613 5 [文献标志码]A Progresses in Synthesis and Application of Metal Phthalocyanines with Axial Ligands CuiNa，JingXiaohui，ChengZhenhua，Bu Tingting，ZhuLUun，XiaDaohong (StateKeyLaboratoryofHeavyOilProcessing，ChinaUniversityofPetroleum，Qingdao Shandong266580，China) [Abstract]Metal phthalocyanines with axial ligands are a kind of coordination compounds with the axial ligands coordinated to central metallic atoms．The two—dimensional macrocyclic co~ugated electronic systems can improve the solubility，stability and optoelectronic properties of the phthalocyanines．In recent years，great achievements have been made in the synthesis and application of the metal phthalocyanines with the axial ligands，especially in the field of solar cell materials．The structure characteristics and synthesis of the metal phthalocyanines with the axial ligands，as well as their application in catalytic oxidation，optical information recording，nonlinear optics，solar cell and medicine，were reviewed．Their development prospects were discussed． [Keywords]metal phthalocyanine；axial ligand；synthesis；photoelectric material 酞菁金属是由18个电子组成的二维大环碘 轭