钴钼基水煤气变换催化剂及其催化反应工艺.pdfVIP

学兔兔 e 譬 石 油 化 工 2011年第40卷第4期 PETROCHEMICAL TECHNOL0GY ·347· ～评一 ～述一 ～约一 一特一 钴钼基水煤气变换催化剂及其催化反应工艺 连奕新，杨意泉，方维平 (厦门大学 化学化工学院 醇醚酯化工清洁生产国家工程实验室，福建 厦门361005) f摘要]介绍了国内外CO变换催化剂的发展及其在不同变换工艺中的应用，阐述了Co—Mo基催化剂的催化机理与硫化方法。 通过综合分析中温变换、中温变换串联低温变换、中温变换串联两段低温变换和全程低温变换4种代表性的工艺流程，提出了高 效节能型的全程低温变换工艺将是变换技术的发展方向，开发适应全程低温变换工艺的高活性和高稳定性的Co—Mo基变换催 化剂及其预硫化技术是今后的主要研究目标。 『关键词]水煤气变换；钴钼基催化剂；全程低温变换；一氧化碳；氧气；二氧化碳 『文章编号]1000—8144(2011)04—0347—11 [中图分类号]TQ 546．4 [文献标识码]A Co-Mo-Based Catalyst and Catalytic Reaction Process for Water-Gas Shift Lian Yixin，Yang Yiquan，Fang Weiping (College of Chemistry and Chemical Engineering，National Engineering Laboratory for Green Chemical Productions of Alcohols Ethers and Esters，Xiamen University，Xiamen Fujian 361005，China) [Abstract] The development background，present situation and developing vista for CO shift catalysts，and the process technologies for water—gas shift reaction both at home and abroad were introduced．The mechanism of the water—gas shift reaction and the characteristic of the catalyst sulfuration methods were also expounded．By comparing the industrial applications of the catalysts in four cross—sectional shift processes，i．e．the high temperature shift，the high—low temperature shift，the high—low—low temperature shift and the total low temperature shift，it can be imagined that to investigate and develop the Co—Mo—based shift catalysts with high activity and stability，which suit the total low—temperature shift process with energy saving，and the preparation procedures f