烧结工艺参数对BeO陶瓷性能地影响.pdf

第 18 卷第 4 期 中国有色金属学报 2008 年 4 月 Vol.18 No.4 The Chinese Journal of Nonferrous Metals Apr. 2008 文章编号：1004-0609(2008)04-0688-05 烧结工艺参数对BeO 陶瓷性能的影响 徐 斌，王日初，余 琨，王小锋，李 敏，杨 军 ( 中南大学 材料科学与工程学院，长沙 410083) 摘 要：采用干压成型和还原气氛烧结的方法制备 BeO 瓷片，采用正交实验方法分析多种烧结工艺参数和不同烧 结助剂对 BeO 瓷片烧结后组织性能的影响。结合 X 射线衍射和 SEM 等方法讨论评价 BeO 陶瓷较好的制备工艺。 结果表明：添加复合助剂 Fe2O3 和 MgO 的瓷片热导率最高，且在相同掺杂条件下，随烧结温度的提高和保温 时间的增长，BeO 陶瓷的热导率也随之提高。在选择的 4 个影响因素中，烧结温度是增加 BeO 陶瓷相对密度 及热导率的重要影响因素，在 1 680 ℃保温 90 min，添加复合助剂 Fe2O3 和 MgO 的瓷片室温热导率最高达 186.3 W/(m·K)。 关键词：BeO 陶瓷；烧结；正交实验；热导率 中图分类号：TB 383 文献标识码：A Effects of sintering parameters on properties of BeO ceramics XU Bin, WANG Ri-chu, YU Kun, WAGN Xiao-feng, LI Min, YANG Jun (School of Materials Science and Engineering, Central South University, Changsha 410083, China) Abstract: The BeO ceramics were prepared by dry pressing moulding and sintering in H atmosphere. The influence of 2 the different additives and sintering techniques on the microstructures and properties of BeO ceramics was studied by X-ray diffraction (XRD) and scanning electronic microscope (SEM). The influence factors were analyzed by orthogonal experiment. The results show that the thermal conductivity of the BeO ceramics with Fe O and MgO is the highest in all 2 3 studied ceramics. And the thermal conductivities in the ceramics increase with the increase of the sintering temperatures and time. The effects of sintering temperatures on the relative densities and the thermal conductivities are