实验六 铅铋含量的连续测定(国外英文资料).docVIP

实验六 铅铋含量的连续测定(国外英文资料) qw导yuiopasdfghjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqlzxcvbnmqwertyuiopasdfghjklzxcvbnmqwehjklzxcvbnmqwertyuiopasdfghjklzxcvbnmqwSo you can use the control solution acidity to make continuous titration. The Pb2 + and Bi3 + are both indicators of the dimethylphenol orange. The dimethylphenol orange is a triphenylmethane indicator, which is soluble in water, and it has a 7-stage acid solution, where H7ln5 - to ln7 - is red. So the color of the solution varies with the acidity of the solution, which is yellow at the pH of 6.3, and the pH 6.3 in red. The combination of xylenol orange with Bi3 + ions and Pb2 + ions is fuchsia, and their stability is weaker than those of Bi3 +, Pb2 + ions and EDTA. Part 1 experimental The main instrument and reagent ZnO (AR) solid 1 + 1 HCl 1 + 1 NH3 · H2O 0.2%, dimethyl phenol orange indicator 200g/L 0.1 mol/L HNO3 solution 0.5 mol/L NaOH solution Precise pH (0.5-5) test paper Lead, bismuth test solution Experimental methods and procedures 1.2.1 EDTA standard solution preparation Concentration is 0.02 mol/LEDTA solution, on the platform scale weigh and ethylenediamine tetraacetic acid disodium 3.8 g, dissolved in 500 ml warm water, such as turbidity, should be filtered. Transfer to 500mL flask and shake well. 1.2.2 zinc standard solution preparation Accurately said in 800-1000 ℃ calcination benchmark of ZnO 0.5 0.6 g in 100 ml beaker, use a small amount of water wetting, chase and then drop add 1 + 1 HCl, add and stir until completely dissolved. Then transfer the solution to the 250mL volumetric flask, dilute to the scale and shake well. 1.2.3 EDTA standard solution calibration with a pipette area 25 ml standard calcium solution, put in conical flask, about 30 ml water, add 2-3 drops of xylenol orange indicator, add 1 + 1 ammonia to solution by yellow steadily pu