第六章 习题答案(国外英文资料).docVIP

第六章 习题答案(国外英文资料) 6-1 in order to determine the shape of synthetic ammonia with iron catalyst irregular shape coefficient, to fill it in the container of inner diameter is 98 mm, filling height of 1 m, and continue to flow for 1 m3 / h of air through the bed, the corresponding measured the pressure drop of bed layer was 101.3 Pa, experimental operation temperature of 298 k, try to calculate the shape coefficient of the catalyst particles. The equivalent volume of the known catalyst particle is 4mm in diameter, the heap density is 1.45 g/cm3, and the particle density is 2.6 g/cm3. Solution: ,, , According to the formula (6-4), the diameter of the outer surface area is equivalent to the diameter of the surface area. According to the form (6-9), that is (1) According to the formula (6-10, 6-11) (2) To substitute the known data, the simultaneous solution (1), (2) : Solution: ? 6-2 by 3 mm diameter of porous spherical catalyst composed of isothermal fixed bed, in which the primary irreversible reaction, based on the catalyst particle volume calculation of reaction rate constant was 0.8 s - 1, effective diffusion coefficient is 0.013 cm2 / s, when the bed height is 2 m, can achieve the required conversion. In order to reduce the pressure drop of the bed layer, the other condition is equal to the spherical catalyst with the diameter of 6mm, the fluid flow in the bed layer is laminar flow, the trial calculation: (1) the catalyst bed height; (2) percentage reduction in bed pressure reduction. Solution: (1) the bed height of a spherical catalyst with a diameter of 6mm Known data:, According to the formula (5-72), the effective factor of the internal diffusion is calculated based on the formula (5-76). , , According to the relation, you have to (3) reduce the percentage of pressure drop in the bed layer of a spherical catalyst with a diameter of 6mm: Depending on the type (6-9), the rate of porosity of the bed layer is the same: (1) The flow of fluid in the bed layer is laminar