聚合物浓度测定方法(国外英文资料).docVIP

聚合物浓度测定方法(国外英文资料)Method of determination of polymer concentration (iodine-starch, iodide))I. instruments and materials1.721 spectrophotometer uv-vis spectrophotometer, and using the model for UV2601, can also be combined with electronic balance and its model, because this is closely related to the final data;2.50ml bottle;3. Pipette;Do not write, still have the cup, the rotor, the agitator, the other volumetric bottle is a plug, only the measuring tube can be plug or notThe polyacrylamide samples should not be listed hereSolution;Cadmium iodide, soluble starch, bromine, hydrate aluminum sulfate;Acetic acid, sodium trihydrate, sodium formate, distilled water. Right? Its all the drugs that are divided into 5 or 6. Can be written as the various solutions required for the following experiment, such as: 5. Saturated bromate 6. Sodium formate solution (1 percent)... .Second, the experimental principleIodine - starch method is of high precision measurement method to determine the concentration of polymer, the determination of the concentration of linear range is 0 to 6 mg/l and the experimental measurement linear range not contradictory?It is. Iodine - starch is using Hofmann rearrangement of the first reaction, under the condition of pH = 5, N - bromine is generated by bromine water and amide group generation of amide, bromine with reducing agent to remove excess. Generated N - bromate bromide generation amide hydrolysis generated time, times of bromate can effect the iodine ion oxide into quantitative iodine, blue three formed under the conditions of the existence of starch iodine - starch complex. Therefore, even if the concentration of amides is very low, it can be efficiently determined by starch iodide method. Iodostarch is based on the amide group and is particularly sensitive to the hydrolysis of polyacrylamide. The iodine-starch method is suitable for the determination of polymer solution concentration in brine and surface water.Three, test methodThe preparation o