负载型柴油氧化脱硫催化剂的研究进展.pdfVIP

学兔兔 石 油 化 工 · 1018· PETROCHEMICAL TECHNOLOGY 20 1 1年第4O卷第9期 负载型柴油氧化脱硫催化剂的研究进展 谢 颖，黄克明，梁朝林 (广东石油化工学院 化工与环境工程学院，广东 茂名525000) [摘要]介绍了负载型柴油氧化脱硫催化剂的研究进展，主要包括负载型过渡金属催化剂和负载型杂多酸催化剂，从催化刹的载 体种类、催化活性和工业应用等方面比较了这两种催化剂的优缺点。通过比较得出，分子筛和活性炭更适合作为氧化脱硫催化剂 的载体；负载型杂多酸催化剂具有活性高、活性组分不易流失、便于分离回收循环使用的优点，具有很好的工业应用前景。 [关键词]柴油；氧化脱硫；负载型催化剂；过渡金属；杂多酸 [文章编号]1000—8144(2011)09—1018—05 [中图分类号]TQ 426 [文献标识码]A Progress on Supported Catalysts for Oxidative Desulfurization of Diesel Xie Ying，Huang Keming，Liang Chaolin (Department of Chemical and Environmental Engineering，Guangdong University of Petrochemical Technology Maoming Guangdong 525000，China) [Abstract]In this paper，the progresses on the supported catalysts for oxidative desulfurization of diesel were discussed，mainly including transition metal catalysts and supported heteropoly acid catalysts．The two kinds of catalysts were compared in support type，catalytic activity and industrial application．It was concluded that zeolite and activated carbon as the supports were suitable to the oxidative desulfurization catalysts． The supported heteropoly acid catalysts had a good industrial prospect due to their high activity，low active component loss，easy separation and multiple reuse for the oxidative desulfurization of diese1． [Keywords]diesel；oxidative desulfurization；supported catalyst；transition metal；heteropoly acid 柴油中的有机硫燃烧会生成SO ，并对环境造 氧化脱硫效果，但催化剂在反应过程中会部分流 成污染，危害人类健康。面对日益严格的柴油硫含