负载型磷钨酸催化剂催化合成生物柴油燃料添加剂.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第12期 PETR0CHEMICAL TECHNOL0GY ·1381· 负载型磷钨酸催化剂催化合成 生物柴油燃料添加剂 任亚辉，张玉军，许元栋，刘 玄 (河南工业大学 化学化工学院，河南 郑州 450001) [摘要]以磷钨酸(TPA)为活性组分、ZrO 为载体，采用浸渍法制备了T队／Zro 负载型催化剂，采用XRD，TG—DTA，BET， FTIR等方法对催化剂的物化性能进行了表征；通过催化甘油与冰醋酸反应制备生物柴油燃料添加剂三醋酸甘油酯，对催化剂 的性能进行了评价，考察了TPA负载量、反应体系、反应温度、反应时间、甘油与冰醋酸的摩尔比、催化剂用量以及不同载 体和载体焙烧温度对三醋酸甘油酯收率的影响。实验结果表明，在优化的反应条件(甘油与冰醋酸的摩尔比1：9、反应温度 130℃、催化剂用量5％(基于甘油的质量)、自生压反应体系下反应4 h)下，5％(W)TPA／ZrO：催化剂(载体焙烧温度为500 oC) 表现出较高的活性，相应的三醋酸甘油酯收率为55．85％。 [关键词]生物柴油；燃料添加剂；三醋酸甘油酯；氧化锆载体；负载型磷钨酸催化剂；甘油；冰醋酸 [文章编号]1000—8144(2014)12—1381—07 [中图分类号]TQ 028．3 [文献标志码]A Acetylation of Glycerol to Biodiesel Fuel Additive over Supported Phosphotungstic Acid Catalyst Ren Yahui，Zhang rujun，Xu Yuandong，LiuXuan (School ofChemistry and Chemical Enginnering，Henan University ofTeehnology，Zhengzhou Henan 450001，China) l Abstract J The TPA／ZrO2 catalysts were prepared by the impregnation of ZrO2 with phosphotungstic acid(TPA)as the active component and characterized by means of XRD，TG—DTA，BET and FTIR． The catalysts were used in the reaction between glycerin and glacial acetic acid to glyceryl triacetate which could be used as a biofuel additive．The effects of TPA loading，reaction pressure，reaction temperature，reaction time，mole ratio of glycerin to glacial acetic acid，catalyst dosage，different supports and their calcination temperature on the yield of glyceryl triacetate were investigated．The results showed that the glyceryl triacetate yield could be 55．85％ under the optimal conditions of TPA loading 5％(W)，calcination temperatur