硅胶负载杂多酸吸附脱除模拟油中的氮化物.pdfVIP

学兔兔 石 油 与 天 然 气 化 工 第 44卷 第 2期 CHEMICAL ENGINEERING OF OIL GAS 硅胶负载杂多酸吸附脱除模拟油中的氮化物 程燕茹 王克强 肖昌宇 张起凯 王 雷 刘 丹 辽宁石油化工大学石油化工学院 摘 要 以硅胶为载体，利用等体积浸渍法负载3种不同杂多酸制备一种吸附剂，以喹啉的十二烷 溶液为模拟油，考察酸负载量、反应时间、反应温度、剂油质量比对油品脱氮率的影响。结果表明，在酸 负载量为4O (砌)，反应温度为5O℃，反应时间为45 min，剂油质量比为1：5的条件下，吸附剂可有效 吸附脱除模拟油中的氮化物，脱氮率达到90 0A以上。采用傅里叶红外光谱(FT—IR)对吸附剂的物化性 质进行了表征。 关键词 硅胶 杂多酸 载体 模拟油 吸附剂 中图分类号：TE624．4 31 文献标志码：A DOI：10．3969／j．issn．1007—3426．2015．02．001 Adsorption and removal of the nitride in simulated oil with silica’supported heteropoly acid Cheng Yanru，Wang Keqiang，Xiao Changyu，Zhang Qikai，Wang Lei，Liu Dan (College of Petrochemical Engineering，Liaoning Shihua University，Fushun 113001，China) Abstract：Using silica gel as a carrier，three different kinds of heteropolyacids were loaded to pre— pare a kind of adsorbent by equal volume impregnation method．Using the mixed solution of quinoline and dodecane as simulated oil，the influence of heteropolyacid loading，reaction time，reaction temper— ature，and mass ratio of adsorbent to oil on denitrification rate of oil were studied．The results showed that under the conditions of the acid loading of 40 ，the reaction temperature of 50℃，the reaction time of 45 minutes．and the mass ratio of adsorbent to oi1 of 1：5，the nitride in the oil can be effec— tively removed with the presence of adsorbent，and the denitrification rate of oil iS more than 9O ． The physical and chemica1 properties of the adsorbent were characterized by FT—IR． Key words：silica gel，heteropo1yacids，carrier，simulated oil，adsorbent 我国原油多属高氮原油口]，氮化物易使催化剂中 制、配合法精制及组合法精制、吸附脱氮、生物脱氮和 毒失活，