硅铝胶老化温度对气相转移法合成MCM-22分子筛的影响.pdfVIP

学兔兔 石 油 化 工 · 34· PETR0CHEMICAL TECHN0L0GY 2011年第40卷第1期 硅铝胶老化温度对气相转移法合成 MCM一22分子筛的影响 刘星生 ，李英霞 (1．江西师范大学 化学化工学院，江西 南昌330022；2．北京化工大学 化工资源有效利用国家重点实验室，北京 100029) [摘要]以硅酸为硅源、偏铝酸钠为铝源制备硅铝胶，采用气相转移法(VPT)合成了MCM一22分子筛。采用TG—DTA， A1 MAS NMR， Si MAS NMR等方法对硅铝胶进行了表征，讨论了硅铝胶老化温度对硅铝胶结构及合成MCM一22分子筛的影响。 实验结果表明，硅铝胶老化温度的改变影响硅铝胶的含水量和sj的存 形式，导致在合成MCM一22分子筛过程中硅铝胶能够提 供的结构单元不一样，从而影响MCM一22分子筛的合成。硅铝胶老化温度为80℃时，硅铝胶的含水量最高，si的存在形式更具 多样性，有利于硅铝胶后期的晶化合成。 [关键词]硅铝胶；老化温度；气相转移法；MCM一22分子筛 [文章编号]1000—8144(2011)01—0034—04 [中图分类号]TQ 424 25 [文献标识码]A Effect of Aluminosilica Gel Aging Temperature on Synthesis of MCM-22 Molecular Sieves by Vapor-Phase Transfer Liu Xingsheng ，Li Yingxia (1．College of Chemistry and Chemical Engineering，Jiangxi Normal University，Nanchang Jiangxi 330022，China； 2．State Key Laboratory of Chemical Resource Engineering，Beijing University of Chemical Technology，Beijing 100029，China) [Abstract] MCM一22 molecular sieves were synthesized through vapor—phase transfer method(VPT) from hexamethylene imine and aluminosilica gels which were prepared from silicic acid and sodium metaaluminate．The aluminosilica gels were characterized by means of TG—DTG． A1 MAS NMR and Si MAS NMR．Effects of aging temperature of the aluminosilica gel on its structure and MCM一22 molecular sieve synthesis were investigated．The results showed that the aging temperature change affected the H2 O content and the Si form in the aluminosilica gel，which could provide different