La对Fe-36Ni低膨胀合金凝固组织的影响.doc

La对Fe-36Ni低膨胀合金凝固组织的影响 于彦冲1，陈伟庆1，郑宏光2 （1. 钢铁冶金新技术国家重点实验室，北京科技大学冶金与生态工程学院，北京，100083；2.宝钢研究院冶金工艺所，上海，201900） 摘要：研究了La对Fe-36Ni低膨胀合金凝固组织的影响，结果表明：加La处理后，合金的凝固组织得到显著改善，随着合金中La含量的增加，凝固组织的等轴晶比例增加，等轴晶尺寸减小，树枝晶变细变短，一次枝晶间距减小，二次枝晶间距基本不变。经La处理后，Fe-36Ni低膨胀合金中形成了大量高熔点的La2O2S颗粒，尺寸约为4μm，错配度计算表明，Fe-36Ni低膨胀合金的低指数面与La2O2S的低指数面有5.42%的较低错配度，因此La2O2S可以作为有效的非均质形核的核心，提高形核率，细化合金的凝固组织。 关键词：Fe-36Ni低膨胀合金；镧；凝固组织；错配度 中图分类号Ni Invar Alloy YU Yan-chong1,CHEN Wei-qing1,ZHENG Hong-guang2 （1. State Key Laboratory of Advanced Metallurgy，School of Metallurgical and Ecological Engineering ,University of Science and Technology Beijing , Beijing 100083 ,China；2. Technology Institute of Metallurgical , Baosteel Institute，Shanghai ,201900） Abstract: The effect of La on the solidification structure of Fe-36Ni invar alloy was investigat- ed .The results showed that the solidification structure of alloy was well improved. The equiaxed grain ratio of solidification structure increased，the equiaxed grain size decreased dendrite became thinner and shorter, the primary dendrite arm spacing decreased, the secondary dendrite arm spacing kept unchanged with the increase of La content. Great amount of high-melting compounds（）with a size of 4um formed in the alloy addition. Based on the theory of lattice misfit, the lattice misfit between low-index surface of Fe-36Ni invar alloy and low-index surface of La2O2S was only 5.42%, which was relatively low. As a result, La2O2S could serve as the core of heterogeneous nucleation, improve nucleation ratio and refine the solidification structure of alloy. Key words: Fe-36Ni invar Alloy ; Lanthanum; Solidification Structure ; Lattice Misfit Fe-36Ni低膨胀合金具有极低的膨胀系数，近年来相关研究工作日趋活跃，并取得显著进展，其产品应用已从传统的精密仪器行业向电子工业和特殊结构材料拓展，需求量越来越大[1-3]。目前，国内Fe-36Ni低膨胀合金主要采用模铸、电渣重熔传统工艺生产，这种工艺成材率偏低，成本较高，生产效率低下。采用立式连铸板坯新工艺可大量生产Fe-36Ni合金，但是连铸板坯热轧时容易开裂。Fe-36Ni是单相奥氏体组织的合金，综合该合金以往的连铸试生产经验，发现其连铸板坯初始凝固组织粗大，可能对热加工性能有较大影响，因此，有必要对Fe-36Ni低膨胀合金进行凝固组织改善的研究。杨晓华等报道了了Ce、Nb、在水冷线材模的条件下对Fe-43Ni合金凝固组织的细化作用，Hideaki SUITO等研究了Ce、