阳离子型稀土金属有机化合物_郁楠.pdfVIP

20 10 化　学　进　展 Vol.20 No.10 2008 10 PROGRESS IN CHEMISTRY 　Oct., 2008 阳离子型稀土金属有机化合物＊ 1, 2 2 ＊＊ 1 ＊＊ 郁　楠 　侯召民 　席振峰 (1.北京大学化学与分子工程学院　北京100871; 2.日本理化学研究所金属有机化学研究室　日本和 市3510198) 　　阳离子型金属有机化合物是催化烯烃聚合反应的活性物种, 其结构与性质直接影响所得聚合 物的微观结构和性能, 具有重要的研究价值。 对四族金属有机化合物的深入研究也推动了对其他前过渡金 属和稀土金属有机化合物的研究。 与为数众多的中性及阴离子型稀土金属有机化合物相比, 由于具有较高 的反应性、合成与分离不易, 阳离子型稀土金属有机化合物直到最近才逐渐得到重视。本文介绍了近年来阳 离子型稀土金属有机化合物的合成、结构和催化烯烃聚合反应领域的研究进展。 　阳离子型金属有机化合物　稀土金属　合成　结构　烯烃聚合催化 :O627.3　:A 　:1005-281X (2008)10-1515-09 Cationic Complexes of Rare Earth Metals 1, 2 2 ＊＊ 1 ＊＊ Yu Nan 　Hou Zhaomin 　X i Zhenf eng (1.College of Chemi try and Molecular Engineering, Peking Univer ity, Beijing 100871, China; 2.Organometallic Chemi try Laboratory, the In titute of Phy ical and Chemical Re earch, Wako City 3510198, Japan) Abstract 　The cationic complexe of tran ition metal erve a catalytically active pecie for olefin polymerization. Their tructure and propertie directly influence the re ulting polymer in term of micro tructure and function.The inten ive inve tigation about cationic alkyl complexe of group 4 metal ha recently prompted intere t in cationic early tran ition metal complexe and rare earth metal complexe .In contra t to the large number of neutral and anionic complexe of rare earth metal , the cationic complexe have remained carce until recently due to their high reactivity and ynthetic difficultie .Thi review ummarize the recent progre in the ynthe i , tructural characterization and olefin polymerization cataly i of the e cationic complexe of rare earth metal . Key words 　cationic complexe of metal ;rare earth metal ;ynthe i ;tructure;olefin polymeriz