毫克当量.pdfVIP

Interconversion of acidity units Scope Procedures are given to allow the interconversion of units of acidity commonly encountered in oenology. Procedure 1. To convert volatile acidity (VA) in g/L as acetic acid to g/L as sulfuric acid: 1.000 g/L as acetic acid (MW = 60.05) = 1.000 moles/L acetic acid 60.05 or = 1.000 equivalents/L 60.05 ie. = 1000 milliequivalents/L (ie. meq/L) 60.05 However, during titration of volatile acids by sodium hydroxide, the stoichiometry of the reaction is such that one mole of acetic acid is neutralised by one mole of sodium hydroxide. Each sulfuric acid molecule has two protons, however, while acetic acid only has one proton; hence the same addition of sodium hydroxide titrant will neutralise only half as many moles of sulfuric acid. ie.: 1.000 moles/L acetic acid = 1.000 x 0.5 moles/L sulfuric acid 60.05 60.05 = 1.000 x 0.5 x 98.08 g/L sulfuric acid 60.05 Thus: 1.000 g/L as acetic acid = 1.000 x 0.5 x 98.08 g/L sulfuric acid 60.05 ie. 1.000 g/L of VA as acetic acid = 0.8167 g/L of VA as sulfuric acid ie. Multiply VA as acetic acid by 0.8167 to give VA as sulfuric acid and Multiply VA as acetic acid by 1000/60.05 to give VA in meq/L Page 1 of 5 2. To convert titratable acidity (TA) in g/L as tartaric acid to g/L as sulfuric acid: 1.000 g/L as tartaric acid (MW = 150.09) =