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DOI: 10.1002/chem.201404295 Full Paper Natural Products |Hot Paper| Formal Total Synthesis of ()-Taxol through Pd-Catalyzed Eight- Membered Carbocyclic Ring Formation Sho Hirai, Masayuki Utsugi, Mitsuhiro Iwamoto, and Masahisa Nakada*[a] Abstract: A formal total synthesis of ()-taxol by a efficiency of the Pd-catalyzed intramolecular alkenylation. convergent approach utilizing Pd-catalyzed intramolecular Rearrangem