全氢菲在分子筛催化剂上环烷环开环反应的研究.PDF

第40卷 第6期 燃摇 料摇 化摇 学摇 学摇 报 Vol.40 No.6 2012年6月 Journal of Fuel Chemistry and Technology Jun. 2012 文章编号:0253鄄2409(2012)06鄄0721鄄06 全氢菲在分子筛催化剂上环烷环开环反应的研究 唐津莲,许友好,汪燮卿 (中国石化 石油化工科学研究院,北京摇 100083) 摘摇 要:在小型固定流化床(FFB)装置上考察了Y与ZSM鄄5分子筛催化剂以及Y分子筛催化剂上温度、剂油比对全氢菲裂 化环烷环开环反应的影响。 结果表明,全氢菲在分子筛催化剂上通过环烷环开环反应生成环己烷、十氢萘等单环或双环环烷 烃;单环或双环环烷烃进一步侧链断裂生成2鄄甲基戊烷、甲基己烷等异构烷烃等,异构化生成二甲基环戊烷、甲乙基环戊烷等 烷基环戊烷,氢转移生成苯、甲苯、二甲苯等烷基苯,进行深度氢转移反应生成萘、烷基萘等双环芳烃;另外,全氢菲也会通过 脱氢缩合生成菲、芘等三环以上芳烃甚至焦炭等。 由于扩散和吸附性能的影响,其裂化开环反应的选择性在Y分子筛催化剂 上比在ZSM鄄5分子筛催化剂上高。 因此,全氢菲环烷环开环与脱氢缩合反应的相对比例(s(NRO)/ s(DHC))在Y分子筛催 化剂上较高;在Y分子筛催化剂上,温度为475~550 益、剂油比为3.0~9.0,反应温度升高或者剂油比增加,双分子氢转移以 及脱氢缩合反应增强,导致环烷环开环反应产物选择性降低。 关键词:多环环烷烃;分子筛催化剂;催化裂化;全氢菲;环烷环开环 中图分类号:TQ031.9摇 摇 文献标识码:A Naphthenic ring opening of perhydrophenanthrene over zeolite catalysts TANG Jin鄄lian,XU You鄄hao,WANG Xie鄄qing (ResearchInstitute of Petroleum Processing,SINOPEC,Beijing摇 10083,China) Abstract:Experiments of perhydrophenanthrene cracking over zeolite catalysts were conducted in a small fixed fluidized bed (FFB) unit. Effects of Y and ZSM鄄5 zeolite catalysts, temperature and catalyst/ oil ratio on naphthenic ring opening reactions of perhydrophenanthrene were examined. The results show that products from naphthenic ring opening reactions of perhydrophenanthrene over zeolite catalysts are monocyclic or dicyclic cycloparaffin (cyclohexane,decalin),which is further converted into isoparaffin (2鄄methylpenptane,methyl hexane)by side chain breaking, or into monocyclic aromatics (benzene, C alkyl benzene) by hydrogen 1~4 transfer,or into dicyclic aromatics (tetrahydronaphthalene,naphthalene,alkyl naphthalene) by deep hydrogen transfer. Produ