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合成堇青石之创新作业技术开发
合成堇青石之創新作業技術開發
An Innovative Cordierite Synthesis Process
1 2 3 3
1 2 3 3
F.S. Yen , P.C. Yu , C.Y. Chen , M.N. Lee
We dev elop ed an inn ov at iv e p r oce ss for
cordierite synthesis using kaolin, talc, and alumina
α- as the raw materials. We examined the size effect
95% of using nano-scaled alumina powders to enhance
1.2x 10-6m/m/ spinel formation during the synthesis and the seeding
effects that normally catalyze to form a new phase
by reducing the kinetic energy. The new synthesis
/ process developed had a total thermal treatment time
of less than 200 minutes. The synthesized cordierite
showed phase purity above 95% with coefficient of
thermal expansion smaller than 1.2x 10-6 m/m/°C.
200 Th e synth esized cor dierit e can b e u sed to
1.2x 10-6m/m/ fabricate honeycomb ceramics for making three-way
catalyst converter.
關鍵詞: Key words: cor di er it e , seedin g , h on ey comb ,
coefficient of thermal expansion
壹、前 言
1.1 堇青石之用途與取得
Cordierite, (Mg,Fe) Al Si O
2 4 5 18
(1)
α β γ( μ) Polymorphs α-
(2) α-
- α-cordierite α-cordierite Indialite
(3)
Hexagonal 1000~ 1350 a c 2.9
-6 o -6 o
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