合成堇青石之创新作业技术开发.PDF

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合成堇青石之创新作业技术开发

合成堇青石之創新作業技術開發 An Innovative Cordierite Synthesis Process 1 2 3 3 1 2 3 3 F.S. Yen , P.C. Yu , C.Y. Chen , M.N. Lee We dev elop ed an inn ov at iv e p r oce ss for cordierite synthesis using kaolin, talc, and alumina α- as the raw materials. We examined the size effect 95% of using nano-scaled alumina powders to enhance 1.2x 10-6m/m/ spinel formation during the synthesis and the seeding effects that normally catalyze to form a new phase by reducing the kinetic energy. The new synthesis / process developed had a total thermal treatment time of less than 200 minutes. The synthesized cordierite showed phase purity above 95% with coefficient of thermal expansion smaller than 1.2x 10-6 m/m/°C. 200 Th e synth esized cor dierit e can b e u sed to 1.2x 10-6m/m/ fabricate honeycomb ceramics for making three-way catalyst converter. 關鍵詞: Key words: cor di er it e , seedin g , h on ey comb , coefficient of thermal expansion 壹、前 言 1.1 堇青石之用途與取得 Cordierite, (Mg,Fe) Al Si O 2 4 5 18 (1) α β γ( μ) Polymorphs α- (2) α- - α-cordierite α-cordierite Indialite (3) Hexagonal 1000~ 1350 a c 2.9 -6 o -6 o

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