温和条件下液态醇催化氧化制醛_酮_陈琳.pdf

16 5 化　学　进　展 Vol.16 No.5 2004 9 PROGRESS IN CHEMISTRY 　Sep ., 2004 温和条件下液态醇催化氧化制醛、酮 陈　琳　许传芝　夏春谷＊ (中国科学院兰州化学物理研究所羰基合成与选择氧化国家重 实验室　兰州730000) 冯艳华 (兰州大学化学化工学院　兰州730000) 　　本文对温和条件下液态醇催化氧化制醛或酮的研究进展进行了全面评述, 介绍了均相催化剂、 液固多相催化剂、有机相-水相两相催化剂、氟两相催化剂和离子液相催化剂, 着重讨论了以O2 为氧源的催 化体系。 　液态醇　催化氧化　均相催化　液固多相催化　水-有机两相催化　氟两相催化　离子液 催化 :O643.32;O622.4 　:A 　:1005-281X(2004 )05-0758-08 Advances in Oxidations of Liquid Alcohols into the Corresponding Carbonyls under Mild Conditions Chen Lin 　Xu Chuanzhi 　Xia Chungu (State Key Labo ato y of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China) Feng Yanhua (College of Chemist y Chemical Enginee ing, Lanzhou Unive sity, Lanzhou 730000, China) Abstract　A eview is p esented on the p og ess in catalytic oxidation of liquid alcohols into the co esponding ca bonyls unde mild conditions.The homogeneous catalysts, liquid-solid hete ogeneous catalysts, o ganic aqueous biphasic catalysts, flou ous biphasic catalysts and ionic liquid phase catalysts a e desc ided.The emphasis is placed on the catalytic systems with O as the oxidant. 2 Key words 　liquid alcohol;catalytic oxidations;homogeneous catalysis;liquid-solid hete ogeneous catalysis; o ganic aqueous biphasic catalysis;f lou ous biphasic catalysis;ionic liquid catalysis 、、、 、　 。 、 , 、O2 、H2O2 [1,2] 。 、。 C 、、, O