碳化钛水基流延膜的制备研究.pdfVIP

第 22 卷第 3 期 陶瓷学报 Vol. 22 ,No. 3 2001 年 9 月 　　　　　　　　　　　　　　 　　　　　　　　　　　　　 Sep. 2001 JOURNAL OF CERAMICS ( ) 　文章编号 :1000 - 2278 2001 03 - 0133 - 05 碳化钛水基流延膜的制备研究 张景贤　江东亮　黄政仁　谭寿洪 ( 中科院上海硅酸盐研究所) 摘 　要 为了提高 TiC 粉体的分散性 ,首先对粉体表面进行处理 ,测定了粉体的 zeta 电位。根据粉体的表面性质,选用阳离子型聚合物 作为分散剂 ,研究了 pH 值、分散剂含量等对 zeta 电位及浆料分散性的影响。采用 PVA 为粘结剂 ,甘油为塑性剂 ,流变测试发现 ,浆 料为触变性流体 ,呈现明显的剪切变稀 ,适合于流延成型。最后 ,制备出了碳化钛流延膜 ,并用 SEM 对得到的流延膜进行了表征。 关键词 　水基流延 ,zeta 电位,分散剂 ,粘结剂 ,塑性剂 ,流变测试 中图法分类号:TQ127. 1 + 2 　　　文献标识码 :A STUDY ON THE AQUEOUS TAPE CASTING OF TiC GREEN SHEETS Zhang Jingxian 　Jiang Dongliang 　Huang Zhenren 　Tan Shouhong ( Shanghai Institute of Ceramics ,China Academy of Science) Abstract ( μ 2 ) The homemade TiC powders D50 = 0. 6 m ,BET = 14. 55m / g are used in this paper. The TiC powders are pre - treated to improve the disperserbility of them in water. According the surface properties of TiC powders as well as the zeta potential date ,a cationic polymer PEI is selected as dispersant. The influence of pH and content of dispersant on the zeta potential and dispersion of TiC slurries are characterized. PVA is selected as binder and glycerol as plasticizer. Rheological measurements show that the slurries exhibit thixotropy behavior ,which is suitable for tape casting. Finally ,the TiC green sheets are prepared and characterized by SEM. Keywords 　aqueous tape casting ,zeta potential ,dispersant ,binder ,plasticizer ,rheological measurement