二元羧酸对草酸钙结晶的调控作用.pdfVIP

25 5 ( ) Vol. 25 No. 5 2004 10 Journal of Jinan University(Natural Science) Oct. 2004 周 娜, 欧阳健明 ( , 510632) [ ] , 012 , 1 L- , . , , ( COM) ( COD) ; , COM COD ; , COM . L- , . [ ] ; ; ; [ ] O614. 23; O623. 621; O781 [ ] A [ ] 1000- 9965(2004) 05- 0600- 04 [ 1] ( CaOxa) , CaOxa 3 , ( COM) ( COD) ( COT) . COMCOD COT , COM COD COT , , COM , , , [ 1] . COD COT , , [ 2, 3] CaOxa . [ 3~ 6] CaOxa . [ 7~ 9] CaOxa , CaOxa , , , . : [ ] 2004- 03- 01 [ ] ( ( 013202) ( 2001C31401) / 0 ( Q02060) [ ] ( 1979- ) , , , : . : E- mail: toyjm@ jnu. e u. cn, Tel: ( 020) 5 : 60 1 1 111 3 ( 1103 g/ cm ) ( 5%) ( 015 mol/ L) ( 012 mol/L) L- , . 112 XRD XtrA X , Cu KA , , 40 kV, 20 mA, 2H5b~ 60b, 0102b/ s. SEM JEOL JSM- T300 Phlips XL- 30 ESEM . . 113 3 5%1103 g/ cm pH 6135, U , 48 h , , 015 mol/L U ( ) , 012 mol/L ( ) , 01030110120015 1 mol/ L . U , ( 27 ? 1) e , CaOxa , . 510 , XRDSEM . COM COD XRD COM ( d = 01593 nm) COD ( d = 01618 nm) ( I M/ I D) . 2 211 0 ( ) 1 ( ) 2 ( ) - OH , 1 - NH ( L- ) , 2 CaOxa . CaOxa , ( COM) ( 1a) . ( 1b) ( 1c) , CaOxa COM . 1 , COM : . L- CaOxa , . ( :5 , 100 , : 200 Lm) 1 1 mol/ L CaOxa SEM 602 (