CuSiO2的表征及其在乙酸乙酯加氢合成乙醇中的催化性能.pdfVIP

石油化工 PETROCHEMICAL TECHNOLOGY • 615 . 2013 年第42 卷第6 期 的表征及其在乙酸乙醋加氢合成 CulSi0 2 乙醇中的催化性能 雷陈明，顾顺超，阎建民，肖文德 200240) (上海交通大学化学化工学院，上海 [摘要]采用尿素均匀沉淀法制备了Cu/SiO，催化剂，用H，-TPR、 XRD和N，吸附-脱附等技术对其进行了表征;将Cu/SiO，催化 剂用于催化乙酸乙酶加氢制备乙醇的反应，考察了反应温度、反应压力、反应物配比和液态空速对乙酸乙酶加氢反应活性和 选择性的影响。表征结果显示， Cu/SiO，催化剂具有较大的比表面积和较低的起始还原温度。实验结果表明，适宜的反应条件 I 为·反应温度220 c、反应压力3.0 MPa、氧气与乙酸乙醋的摩尔比60 、液态空速1.0 h- ，在此条件下，乙酸乙醋转化率可达 96.2% ，乙醇选择性为97.8%。 [关键词]铜/二氧化硅催化剂;均匀沉淀法;乙酸乙醋;加氢;乙醇 [文章编号 J 1000 - 8144 (2013 )06 - 0615 - 05 [中图分类号 J TQ426 [文献标志码 J A Characterization of CulSi02 Catalyst and 1臼 Performance in Hydrogenation of Ethyl Acetate to Ethanol Lei Chenming , Gu Shunchao , Yan Jianmin , Xiao Wende (School of Chemistry and Chemical Engineering , Shanghai Jiao Tong University , Shanghai 200240 , China) [ Abstract ] A Cu/Si02 catalyst was prepared by a homogeneous precipitation method with urea as the precipitant , characterized by means of H2- TPR , XRD and BET , and used in the hydrogenation of ethyl acetate to ethanol. The effects of temperature , pressure , mole ratio of H2 to ethyl acetate and LHSV on the activity and selectivity ofthe catalyst were investigated. The results show that the catalyst has high specific surface area and low initial reduction temperature. The catalyst performance in the